Highly Efficient and Thermally Stable Electro-optic Polymer from a Smartly Controlled Crosslinking Process

Jingdong Luo; Marine Haller; Hongxiang Li; Tae-Dong Kim; Alex K.-Y. Jen

doi:10.1002/adma.200305202

Highly Efficient and Thermally Stable Electro-optic Polymer from a Smartly Controlled Crosslinking Process

Jingdong Luo, Marine Haller, Hongxiang Li, Tae-Dong Kim, Alex K.-Y. Jen

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

76 Citations (Scopus)

Abstract

A nonlinear optical polymer, which is thermoreversibly crosslinkable (see Figure), has been developed to overcome the nonlinearity–stability trade‐off in poled polymers. High poling efficiency has been achieved after controlled, mild lattice hardening via the Diels–Alder crosslinking reaction. The resulting material exhibits a large electro‐optic coefficient (r₃₃ = 76 pm V^–1 at 1.3 μm) and excellent temporal stability.

Original language	English
Pages (from-to)	1635-1638
Journal	Advanced Materials
Volume	15
Issue number	19
Online published	7 Oct 2003
DOIs	https://doi.org/10.1002/adma.200305202
Publication status	Published - Oct 2003
Externally published	Yes

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abstract = "A nonlinear optical polymer, which is thermoreversibly crosslinkable (see Figure), has been developed to overcome the nonlinearity–stability trade‐off in poled polymers. High poling efficiency has been achieved after controlled, mild lattice hardening via the Diels–Alder crosslinking reaction. The resulting material exhibits a large electro‐optic coefficient (r33 = 76 pm V–1 at 1.3 μm) and excellent temporal stability. ",

author = "Jingdong Luo and Marine Haller and Hongxiang Li and Tae-Dong Kim and Jen, {Alex K.-Y.}",

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AU - Luo, Jingdong

AU - Haller, Marine

AU - Li, Hongxiang

AU - Kim, Tae-Dong

AU - Jen, Alex K.-Y.

PY - 2003/10

Y1 - 2003/10

N2 - A nonlinear optical polymer, which is thermoreversibly crosslinkable (see Figure), has been developed to overcome the nonlinearity–stability trade‐off in poled polymers. High poling efficiency has been achieved after controlled, mild lattice hardening via the Diels–Alder crosslinking reaction. The resulting material exhibits a large electro‐optic coefficient (r33 = 76 pm V–1 at 1.3 μm) and excellent temporal stability.

AB - A nonlinear optical polymer, which is thermoreversibly crosslinkable (see Figure), has been developed to overcome the nonlinearity–stability trade‐off in poled polymers. High poling efficiency has been achieved after controlled, mild lattice hardening via the Diels–Alder crosslinking reaction. The resulting material exhibits a large electro‐optic coefficient (r33 = 76 pm V–1 at 1.3 μm) and excellent temporal stability.

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U2 - 10.1002/adma.200305202

DO - 10.1002/adma.200305202

M3 - RGC 21 - Publication in refereed journal

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SP - 1635

EP - 1638

JO - Advanced Materials

JF - Advanced Materials

IS - 19

ER -

Highly Efficient and Thermally Stable Electro-optic Polymer from a Smartly Controlled Crosslinking Process

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