High-resolution energy-selected study of the reaction CH3X+→CH3 ++X: Accurate thermochemistry for the CH3X/CH3X+ (X=Br, I) system

Y. Song; X. M. Qian; K. C. Lau; C. Y. Ng; Jianbo Liu; Wenwu Chen

doi:10.1063/1.1391268

High-resolution energy-selected study of the reaction CH₃X⁺→CH₃ ⁺+X: Accurate thermochemistry for the CH₃X/CH₃X⁺ (X=Br, I) system

Y. Song
, X. M. Qian
, K. C. Lau
, C. Y. Ng
, Jianbo Liu
, Wenwu Chen

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

49 Citations (Scopus)

Abstract

The formation of methyl cations from the dissociation of energy selected methyl halides near their dissociation thresholds was investigated. High-resolution pulsed field ionization-photoelectron (PFI-PE) and PFI-PE-photoion coincidence (PFI-PEPICO) techniques were used for the analysis. A highly reliable value of the heat of formation of these compounds were obtained from the results.

Original language	English
Pages (from-to)	4095-4104
Journal	Journal of Chemical Physics
Volume	115
Issue number	9
DOIs	https://doi.org/10.1063/1.1391268
Publication status	Published - 1 Sept 2001
Externally published	Yes

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title = "High-resolution energy-selected study of the reaction CH3X+→CH3 ++X: Accurate thermochemistry for the CH3X/CH3X+ (X=Br, I) system",

abstract = "The formation of methyl cations from the dissociation of energy selected methyl halides near their dissociation thresholds was investigated. High-resolution pulsed field ionization-photoelectron (PFI-PE) and PFI-PE-photoion coincidence (PFI-PEPICO) techniques were used for the analysis. A highly reliable value of the heat of formation of these compounds were obtained from the results.",

author = "Y. Song and Qian, \{X. M.\} and Lau, \{K. C.\} and Ng, \{C. Y.\} and Jianbo Liu and Wenwu Chen",

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T2 - Accurate thermochemistry for the CH3X/CH3X+ (X=Br, I) system

AU - Song, Y.

AU - Qian, X. M.

AU - Lau, K. C.

AU - Ng, C. Y.

AU - Liu, Jianbo

AU - Chen, Wenwu

PY - 2001/9/1

Y1 - 2001/9/1

N2 - The formation of methyl cations from the dissociation of energy selected methyl halides near their dissociation thresholds was investigated. High-resolution pulsed field ionization-photoelectron (PFI-PE) and PFI-PE-photoion coincidence (PFI-PEPICO) techniques were used for the analysis. A highly reliable value of the heat of formation of these compounds were obtained from the results.

AB - The formation of methyl cations from the dissociation of energy selected methyl halides near their dissociation thresholds was investigated. High-resolution pulsed field ionization-photoelectron (PFI-PE) and PFI-PE-photoion coincidence (PFI-PEPICO) techniques were used for the analysis. A highly reliable value of the heat of formation of these compounds were obtained from the results.

UR - https://www.scopus.com/pages/publications/0035448799

UR - https://www.scopus.com/pages/publications/0035448799#tab=impact

U2 - 10.1063/1.1391268

DO - 10.1063/1.1391268

M3 - RGC 21 - Publication in refereed journal

SN - 0021-9606

VL - 115

SP - 4095

EP - 4104

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 9

ER -