High dielectric composition in the system sn-modified (1-x)BaTiO 3-xBa(Cu1/3Nb2/3)O3, x=0.025 for multilayer ceramic capacitors

Deepam Maurya; Cheol-Woo Ahn; Shujun Zhang; Shashank Priya

doi:10.1111/j.1551-2916.2009.03523.x

High dielectric composition in the system sn-modified (1-x)BaTiO ₃-xBa(Cu_1/3Nb_2/3)O₃, x=0.025 for multilayer ceramic capacitors

Deepam Maurya
, Cheol-Woo Ahn
, Shujun Zhang
, Shashank Priya

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

22 Citations (Scopus)

Abstract

We report the synthesis and characterization of BaTiO₃ (BT)-based high dielectric compositions that are promising for Y5V-type multilayer ceramic capacitors. A solid solution with a nominal composition (1-x)BaTiO₃-xBa(Cu_1/3Nb_2/3)O₃ (BCN) (x=0, 0.025) was synthesized by conventional mixed oxide route, followed by compositional modification with varying concentration of Sn, as given by the formulation: 0.975 BaTi_1-ySn_yO₃-0.025 Ba(Cu_1/3Nb_2/3)O₃ (y=0.05, 0.06, 0.075, 0.1). Room-temperature (RT) X-ray diffraction patterns showed a decrease in the tetragonality of BT after modifying with BCN (BTBCN). Modifications with Sn lead to a further decrement in tetragonality and the RT structure became cubic at 6.0 at.% doping level. The decrement in tetragonality was accompanied by lowering of Curie temperature (T_c). BTBCN doped with 6 and 7.5 at.% Sn were found to exhibit diffuse phase transition accompanied by a high dielectric constant ≥7000, a low loss tangent ≤1% and a grain size in the submicrometer regime (≤1 μm). © 2010 The American Ceramic Society.

Original language	English
Pages (from-to)	1225-1228
Journal	Journal of the American Ceramic Society
Volume	93
Issue number	5
DOIs	https://doi.org/10.1111/j.1551-2916.2009.03523.x
Publication status	Published - May 2010
Externally published	Yes

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Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

Funding

This work was ﬁnancially supported by National Science Foundation (NSF) and Korea Institute of Materials Science (KIMS).

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@article{7ade8b0953bd43219d087fb8e9b3ab25,

title = "High dielectric composition in the system sn-modified (1-x)BaTiO 3-xBa(Cu1/3Nb2/3)O3, x=0.025 for multilayer ceramic capacitors",

abstract = "We report the synthesis and characterization of BaTiO3 (BT)-based high dielectric compositions that are promising for Y5V-type multilayer ceramic capacitors. A solid solution with a nominal composition (1-x)BaTiO3-xBa(Cu1/3Nb2/3)O3 (BCN) (x=0, 0.025) was synthesized by conventional mixed oxide route, followed by compositional modification with varying concentration of Sn, as given by the formulation: 0.975 BaTi1-ySnyO3-0.025 Ba(Cu1/3Nb2/3)O3 (y=0.05, 0.06, 0.075, 0.1). Room-temperature (RT) X-ray diffraction patterns showed a decrease in the tetragonality of BT after modifying with BCN (BTBCN). Modifications with Sn lead to a further decrement in tetragonality and the RT structure became cubic at 6.0 at.\% doping level. The decrement in tetragonality was accompanied by lowering of Curie temperature (Tc). BTBCN doped with 6 and 7.5 at.\% Sn were found to exhibit diffuse phase transition accompanied by a high dielectric constant ≥7000, a low loss tangent ≤1\% and a grain size in the submicrometer regime (≤1 μm). {\textcopyright} 2010 The American Ceramic Society.",

author = "Deepam Maurya and Cheol-Woo Ahn and Shujun Zhang and Shashank Priya",

note = "Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].",

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doi = "10.1111/j.1551-2916.2009.03523.x",

language = "English",

volume = "93",

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High dielectric composition in the system sn-modified (1-x)BaTiO ₃-xBa(Cu_1/3Nb_2/3)O₃, x=0.025 for multilayer ceramic capacitors. / Maurya, Deepam; Ahn, Cheol-Woo; Zhang, Shujun et al.
In: Journal of the American Ceramic Society, Vol. 93, No. 5, 05.2010, p. 1225-1228.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

TY - JOUR

T1 - High dielectric composition in the system sn-modified (1-x)BaTiO 3-xBa(Cu1/3Nb2/3)O3, x=0.025 for multilayer ceramic capacitors

AU - Maurya, Deepam

AU - Ahn, Cheol-Woo

AU - Zhang, Shujun

AU - Priya, Shashank

N1 - Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

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N2 - We report the synthesis and characterization of BaTiO3 (BT)-based high dielectric compositions that are promising for Y5V-type multilayer ceramic capacitors. A solid solution with a nominal composition (1-x)BaTiO3-xBa(Cu1/3Nb2/3)O3 (BCN) (x=0, 0.025) was synthesized by conventional mixed oxide route, followed by compositional modification with varying concentration of Sn, as given by the formulation: 0.975 BaTi1-ySnyO3-0.025 Ba(Cu1/3Nb2/3)O3 (y=0.05, 0.06, 0.075, 0.1). Room-temperature (RT) X-ray diffraction patterns showed a decrease in the tetragonality of BT after modifying with BCN (BTBCN). Modifications with Sn lead to a further decrement in tetragonality and the RT structure became cubic at 6.0 at.% doping level. The decrement in tetragonality was accompanied by lowering of Curie temperature (Tc). BTBCN doped with 6 and 7.5 at.% Sn were found to exhibit diffuse phase transition accompanied by a high dielectric constant ≥7000, a low loss tangent ≤1% and a grain size in the submicrometer regime (≤1 μm). © 2010 The American Ceramic Society.

AB - We report the synthesis and characterization of BaTiO3 (BT)-based high dielectric compositions that are promising for Y5V-type multilayer ceramic capacitors. A solid solution with a nominal composition (1-x)BaTiO3-xBa(Cu1/3Nb2/3)O3 (BCN) (x=0, 0.025) was synthesized by conventional mixed oxide route, followed by compositional modification with varying concentration of Sn, as given by the formulation: 0.975 BaTi1-ySnyO3-0.025 Ba(Cu1/3Nb2/3)O3 (y=0.05, 0.06, 0.075, 0.1). Room-temperature (RT) X-ray diffraction patterns showed a decrease in the tetragonality of BT after modifying with BCN (BTBCN). Modifications with Sn lead to a further decrement in tetragonality and the RT structure became cubic at 6.0 at.% doping level. The decrement in tetragonality was accompanied by lowering of Curie temperature (Tc). BTBCN doped with 6 and 7.5 at.% Sn were found to exhibit diffuse phase transition accompanied by a high dielectric constant ≥7000, a low loss tangent ≤1% and a grain size in the submicrometer regime (≤1 μm). © 2010 The American Ceramic Society.

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