Hierarchical Porous NiO/β-NiMoO4 Heterostructure as Superior Anode Material for Lithium Storage

Zhijian Wang; Shilin Zhang; Hai Zeng; Haimin Zhao; Wei Sun; Meng Jiang; Chuanqi Feng; Jianwen Liu; Tengfei Zhou; Yang Zheng; Zaiping Guo

doi:10.1002/cplu.201800220

Hierarchical Porous NiO/β-NiMoO₄ Heterostructure as Superior Anode Material for Lithium Storage

Zhijian Wang
, Shilin Zhang
, Hai Zeng
, Haimin Zhao
, Wei Sun
, Meng Jiang
, Chuanqi Feng
, Jianwen Liu
, Tengfei Zhou
, Yang Zheng^*
, Zaiping Guo

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

20 Citations (Scopus)

Abstract

Ternary transition metal oxides (TTMOs) have attracted considerable attention for rechargeable batteries because of their fascinating properties. However, the unsatisfactory electrochemical performance originating from the poor intrinsic electronic conductivity and inferior structural stability impedes their practical applications. Here, the novel hierarchical porous NiO/β-NiMoO4 heterostructure is fabricated, and exhibits high reversible capacity, superior rate capability, and excellent cycling stability in Li-ion batteries (LIBs), which is much better than the corresponding single-phase NiMoO4 and NiO materials. The significantly enhanced electrochemical properties can be attributed to its superior structural characteristics, including the large surface area, abundant pores, fast charge transfer, and catalytic effect of the intermediate product of metallic nickel. The NiO/β-NiMoO4 heterostructure delivers a high capacity of 1314 mA h g−1 at 0.2 A g−1 after 100 cycles. Furthermore, even after 400 cycles at 1 A g−1, the reversible capacity remains at around 500 mA h g−1. These results indicate that the NiO/β-NiMoO4 heterostructure shows great potential as an anode material for high-performance LIBs. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Original language	English
Pages (from-to)	915-923
Journal	ChemPlusChem
Volume	83
Issue number	10
DOIs	https://doi.org/10.1002/cplu.201800220
Publication status	Published - 1 Oct 2018
Externally published	Yes

Bibliographical note

Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

Funding

Financial support provided by the grant from the National Natural Science Foundation of China (No. 21476063) and the Hubei Provincial Natural Science Foundation of China (2018CFB237) is gratefully acknowledged.

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Research Keywords

electrochemistry
heterostructures
Li-ion batteries
nanostructures
ternary transition metal oxides

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10.1002/cplu.201800220

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Cite this

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title = "Hierarchical Porous NiO/β-NiMoO4 Heterostructure as Superior Anode Material for Lithium Storage",

abstract = "Ternary transition metal oxides (TTMOs) have attracted considerable attention for rechargeable batteries because of their fascinating properties. However, the unsatisfactory electrochemical performance originating from the poor intrinsic electronic conductivity and inferior structural stability impedes their practical applications. Here, the novel hierarchical porous NiO/β-NiMoO4 heterostructure is fabricated, and exhibits high reversible capacity, superior rate capability, and excellent cycling stability in Li-ion batteries (LIBs), which is much better than the corresponding single-phase NiMoO4 and NiO materials. The significantly enhanced electrochemical properties can be attributed to its superior structural characteristics, including the large surface area, abundant pores, fast charge transfer, and catalytic effect of the intermediate product of metallic nickel. The NiO/β-NiMoO4 heterostructure delivers a high capacity of 1314 mA h g−1 at 0.2 A g−1 after 100 cycles. Furthermore, even after 400 cycles at 1 A g−1, the reversible capacity remains at around 500 mA h g−1. These results indicate that the NiO/β-NiMoO4 heterostructure shows great potential as an anode material for high-performance LIBs. {\textcopyright} 2018 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

keywords = "electrochemistry, heterostructures, Li-ion batteries, nanostructures, ternary transition metal oxides",

author = "Zhijian Wang and Shilin Zhang and Hai Zeng and Haimin Zhao and Wei Sun and Meng Jiang and Chuanqi Feng and Jianwen Liu and Tengfei Zhou and Yang Zheng and Zaiping Guo",

note = "Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].",

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T1 - Hierarchical Porous NiO/β-NiMoO4 Heterostructure as Superior Anode Material for Lithium Storage

AU - Wang, Zhijian

AU - Zhang, Shilin

AU - Zeng, Hai

AU - Zhao, Haimin

AU - Sun, Wei

AU - Jiang, Meng

AU - Feng, Chuanqi

AU - Liu, Jianwen

AU - Zhou, Tengfei

AU - Zheng, Yang

AU - Guo, Zaiping

N1 - Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

PY - 2018/10/1

Y1 - 2018/10/1

N2 - Ternary transition metal oxides (TTMOs) have attracted considerable attention for rechargeable batteries because of their fascinating properties. However, the unsatisfactory electrochemical performance originating from the poor intrinsic electronic conductivity and inferior structural stability impedes their practical applications. Here, the novel hierarchical porous NiO/β-NiMoO4 heterostructure is fabricated, and exhibits high reversible capacity, superior rate capability, and excellent cycling stability in Li-ion batteries (LIBs), which is much better than the corresponding single-phase NiMoO4 and NiO materials. The significantly enhanced electrochemical properties can be attributed to its superior structural characteristics, including the large surface area, abundant pores, fast charge transfer, and catalytic effect of the intermediate product of metallic nickel. The NiO/β-NiMoO4 heterostructure delivers a high capacity of 1314 mA h g−1 at 0.2 A g−1 after 100 cycles. Furthermore, even after 400 cycles at 1 A g−1, the reversible capacity remains at around 500 mA h g−1. These results indicate that the NiO/β-NiMoO4 heterostructure shows great potential as an anode material for high-performance LIBs. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

AB - Ternary transition metal oxides (TTMOs) have attracted considerable attention for rechargeable batteries because of their fascinating properties. However, the unsatisfactory electrochemical performance originating from the poor intrinsic electronic conductivity and inferior structural stability impedes their practical applications. Here, the novel hierarchical porous NiO/β-NiMoO4 heterostructure is fabricated, and exhibits high reversible capacity, superior rate capability, and excellent cycling stability in Li-ion batteries (LIBs), which is much better than the corresponding single-phase NiMoO4 and NiO materials. The significantly enhanced electrochemical properties can be attributed to its superior structural characteristics, including the large surface area, abundant pores, fast charge transfer, and catalytic effect of the intermediate product of metallic nickel. The NiO/β-NiMoO4 heterostructure delivers a high capacity of 1314 mA h g−1 at 0.2 A g−1 after 100 cycles. Furthermore, even after 400 cycles at 1 A g−1, the reversible capacity remains at around 500 mA h g−1. These results indicate that the NiO/β-NiMoO4 heterostructure shows great potential as an anode material for high-performance LIBs. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

KW - electrochemistry

KW - heterostructures

KW - Li-ion batteries

KW - nanostructures

KW - ternary transition metal oxides

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