Heterosite reactivity of cobalt-rhodium mixed- metal clusters

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

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Detail(s)

Original languageEnglish
Pages (from-to)2345-2349
Journal / PublicationPolyhedron
Volume7
Issue number22-23
Publication statusPublished - 1988
Externally publishedYes

Abstract

It has been established that reactions of cobalt-rhodium mixed-metal clusters with nucleophiles such as PEt3, THF, MeCN and Cl- occur on the rhodium site, with alkynes on the cobalt site. Several reversible tetranuclear-dinuclear transformations were observed with preferential retainment of the cobalt-rhodium bond. © 1988.

Citation Format(s)

Heterosite reactivity of cobalt-rhodium mixed- metal clusters. / Horvath, Istvan T.
In: Polyhedron, Vol. 7, No. 22-23, 1988, p. 2345-2349.

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review