Heterosite reactivity of cobalt-rhodium mixed- metal clusters

Istvan T. Horvath

doi:10.1016/S0277-5387(00)86352-4

Heterosite reactivity of cobalt-rhodium mixed- metal clusters

Istvan T. Horvath

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

19 Citations (Scopus)

Abstract

It has been established that reactions of cobalt-rhodium mixed-metal clusters with nucleophiles such as PEt₃, THF, MeCN and Cl^- occur on the rhodium site, with alkynes on the cobalt site. Several reversible tetranuclear-dinuclear transformations were observed with preferential retainment of the cobalt-rhodium bond. © 1988.

Original language	English
Pages (from-to)	2345-2349
Journal	Polyhedron
Volume	7
Issue number	22-23
DOIs	https://doi.org/10.1016/S0277-5387(00)86352-4
Publication status	Published - 1988
Externally published	Yes

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title = "Heterosite reactivity of cobalt-rhodium mixed- metal clusters",

abstract = "It has been established that reactions of cobalt-rhodium mixed-metal clusters with nucleophiles such as PEt3, THF, MeCN and Cl- occur on the rhodium site, with alkynes on the cobalt site. Several reversible tetranuclear-dinuclear transformations were observed with preferential retainment of the cobalt-rhodium bond. {\textcopyright} 1988.",

author = "Horvath, \{Istvan T.\}",

year = "1988",

doi = "10.1016/S0277-5387(00)86352-4",

language = "English",

volume = "7",

pages = "2345--2349",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd.",

number = "22-23",

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TY - JOUR

T1 - Heterosite reactivity of cobalt-rhodium mixed- metal clusters

AU - Horvath, Istvan T.

PY - 1988

Y1 - 1988

N2 - It has been established that reactions of cobalt-rhodium mixed-metal clusters with nucleophiles such as PEt3, THF, MeCN and Cl- occur on the rhodium site, with alkynes on the cobalt site. Several reversible tetranuclear-dinuclear transformations were observed with preferential retainment of the cobalt-rhodium bond. © 1988.

AB - It has been established that reactions of cobalt-rhodium mixed-metal clusters with nucleophiles such as PEt3, THF, MeCN and Cl- occur on the rhodium site, with alkynes on the cobalt site. Several reversible tetranuclear-dinuclear transformations were observed with preferential retainment of the cobalt-rhodium bond. © 1988.

UR - https://www.scopus.com/pages/publications/0000193530

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-0000193530&origin=recordpage

U2 - 10.1016/S0277-5387(00)86352-4

DO - 10.1016/S0277-5387(00)86352-4

M3 - RGC 21 - Publication in refereed journal

SN - 0277-5387

VL - 7

SP - 2345

EP - 2349

JO - Polyhedron

JF - Polyhedron

IS - 22-23

ER -

Heterosite reactivity of cobalt-rhodium mixed- metal clusters

Abstract

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