Heterometallic carbonyl cluster oxide. Formation, structure and reactivity of WRe2 oxo-acetylide cluster compounds

Yun Chi; Puu-Shum Cheng; Hsiao-Ling Wu; Der-Kweng Hwang; Pei-Chiun Su; Shie-Ming Peng; Gene-Hsiang Lee

doi:10.1039/C39940001839

Author(s)

Puu-Shum Cheng
Hsiao-Ling Wu
Der-Kweng Hwang
Pei-Chiun Su
Shie-Ming Peng
Gene-Hsiang Lee

Detail(s)

Original language	English
Pages (from-to)	1839-1840
Journal / Publication	Journal of the Chemical Society, Chemical Communications
Issue number	16
Publication status	Published - 1994
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1039/C39940001839 Final Published version
	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-37049082148&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(4716bac7-4e59-4042-a543-54f2464e42a1).html

Abstract

Cluster [WRe₂(C₅Me₅)(O)(CO) ₈(CCPh)] 1a possessing a terminal oxo ligand is prepared by treatment of the acetylide cluster [WRe₂(C₅Me₅)(CO) ₉(CCPh)] with O₂ or N₂O; hydrogenation of 1a affords three isolable clusters, showing an example of oxo-ligand mediated sequential conversion of acetylide to alkenyl and alkylidene.

Citation Format(s)

[ RIS ] [ BibTeX ]

Heterometallic carbonyl cluster oxide. Formation, structure and reactivity of WRe₂ oxo-acetylide cluster compounds. / Chi, Yun; Cheng, Puu-Shum; Wu, Hsiao-Ling et al.

In: Journal of the Chemical Society, Chemical Communications, No. 16, 1994, p. 1839-1840.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

Chi, Y, Cheng, P-S, Wu, H-L, Hwang, D-K, Su, P-C, Peng, S-M & Lee, G-H 1994, 'Heterometallic carbonyl cluster oxide. Formation, structure and reactivity of WRe₂ oxo-acetylide cluster compounds', Journal of the Chemical Society, Chemical Communications, no. 16, pp. 1839-1840. https://doi.org/10.1039/C39940001839

Chi, Y., Cheng, P-S., Wu, H-L., Hwang, D-K., Su, P-C., Peng, S-M., & Lee, G-H. (1994). Heterometallic carbonyl cluster oxide. Formation, structure and reactivity of WRe₂ oxo-acetylide cluster compounds. Journal of the Chemical Society, Chemical Communications, (16), 1839-1840. https://doi.org/10.1039/C39940001839

Chi Y, Cheng P-S, Wu H-L, Hwang D-K, Su P-C, Peng S-M et al. Heterometallic carbonyl cluster oxide. Formation, structure and reactivity of WRe₂ oxo-acetylide cluster compounds. Journal of the Chemical Society, Chemical Communications. 1994;(16):1839-1840. doi: 10.1039/C39940001839

Chi, Yun ; Cheng, Puu-Shum ; Wu, Hsiao-Ling et al. / Heterometallic carbonyl cluster oxide. Formation, structure and reactivity of WRe₂ oxo-acetylide cluster compounds. In: Journal of the Chemical Society, Chemical Communications. 1994 ; No. 16. pp. 1839-1840.