Heterometallic carbonyl cluster oxide. Formation, structure and reactivity of WRe2 oxo-acetylide cluster compounds

Yun Chi; Puu-Shum Cheng; Hsiao-Ling Wu; Der-Kweng Hwang; Pei-Chiun Su; Shie-Ming Peng; Gene-Hsiang Lee

doi:10.1039/C39940001839

Heterometallic carbonyl cluster oxide. Formation, structure and reactivity of WRe₂ oxo-acetylide cluster compounds

Yun Chi, Puu-Shum Cheng, Hsiao-Ling Wu, Der-Kweng Hwang, Pei-Chiun Su, Shie-Ming Peng, Gene-Hsiang Lee

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

19 Citations (Scopus)

Abstract

Cluster [WRe₂(C₅Me₅)(O)(CO) ₈(CCPh)] 1a possessing a terminal oxo ligand is prepared by treatment of the acetylide cluster [WRe₂(C₅Me₅)(CO) ₉(CCPh)] with O₂ or N₂O; hydrogenation of 1a affords three isolable clusters, showing an example of oxo-ligand mediated sequential conversion of acetylide to alkenyl and alkylidene.

Original language	English
Pages (from-to)	1839-1840
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/C39940001839
Publication status	Published - 1994
Externally published	Yes

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title = "Heterometallic carbonyl cluster oxide. Formation, structure and reactivity of WRe2 oxo-acetylide cluster compounds",

abstract = "Cluster [WRe2(C5Me5)(O)(CO) 8(CCPh)] 1a possessing a terminal oxo ligand is prepared by treatment of the acetylide cluster [WRe2(C5Me5)(CO) 9(CCPh)] with O2 or N2O; hydrogenation of 1a affords three isolable clusters, showing an example of oxo-ligand mediated sequential conversion of acetylide to alkenyl and alkylidene.",

author = "Yun Chi and Puu-Shum Cheng and Hsiao-Ling Wu and Der-Kweng Hwang and Pei-Chiun Su and Shie-Ming Peng and Gene-Hsiang Lee",

year = "1994",

doi = "10.1039/C39940001839",

language = "English",

pages = "1839--1840",

journal = "Journal of the Chemical Society, Chemical Communications",

issn = "0022-4936",

publisher = "Royal Society of Chemistry",

number = "16",

}

TY - JOUR

T1 - Heterometallic carbonyl cluster oxide. Formation, structure and reactivity of WRe2 oxo-acetylide cluster compounds

AU - Chi, Yun

AU - Cheng, Puu-Shum

AU - Wu, Hsiao-Ling

AU - Hwang, Der-Kweng

AU - Su, Pei-Chiun

AU - Peng, Shie-Ming

AU - Lee, Gene-Hsiang

PY - 1994

Y1 - 1994

N2 - Cluster [WRe2(C5Me5)(O)(CO) 8(CCPh)] 1a possessing a terminal oxo ligand is prepared by treatment of the acetylide cluster [WRe2(C5Me5)(CO) 9(CCPh)] with O2 or N2O; hydrogenation of 1a affords three isolable clusters, showing an example of oxo-ligand mediated sequential conversion of acetylide to alkenyl and alkylidene.

AB - Cluster [WRe2(C5Me5)(O)(CO) 8(CCPh)] 1a possessing a terminal oxo ligand is prepared by treatment of the acetylide cluster [WRe2(C5Me5)(CO) 9(CCPh)] with O2 or N2O; hydrogenation of 1a affords three isolable clusters, showing an example of oxo-ligand mediated sequential conversion of acetylide to alkenyl and alkylidene.

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UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-37049082148&origin=recordpage

U2 - 10.1039/C39940001839

DO - 10.1039/C39940001839

M3 - RGC 21 - Publication in refereed journal

SN - 0022-4936

SP - 1839

EP - 1840

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 16

ER -