Abstract
SnO2 nanocrystals (NCs) with spherical, cubic, and cuboid nanorod morphologies are obtained at different stages in hydrothermal synthesis using a SnCl4 5 H2 O to CO (NH2)2 ratio of 1 to 10. Microstructural examination and theoretical derivation reveal that small spherical NCs are formed initially and some of them morph into cylindrical NCs because of the low surface free energy. These NCs transform into bigger cubic NCs with time finally evolving into cuboid nanorods due to Brownian motion. The cuboid nanorods have a lower surface free energy than the cubic NCs and constitute a stable nanostructure. © 2011 American Institute of Physics.
| Original language | English |
|---|---|
| Article number | 133102 |
| Journal | Applied Physics Letters |
| Volume | 98 |
| Issue number | 13 |
| DOIs | |
| Publication status | Published - 28 Mar 2011 |
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