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Growth of mullite whiskers in mechanochemically activated oxides doped with WO3

  • L.B. Kong*
  • , H. Huang
  • , T.S. Zhang
  • , J. Ma
  • , F. Boey
  • , R.F. Zhang
  • , Z.H. Wang
  • *Corresponding author for this work

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

Abstract

The effect of WO3 on mullite formation and mullite whisker morphology, in oxide mixtures activated by a high-energy ball milling process, was investigated. Differential thermal analysis (DTA) measurement indicated that WO3 enhanced the mullite phase formation, with mullitization temperature of 951 °C, 921 °C and 835 °C for the samples doped with 5, 10 and 20 mol% WO3, respectively. However, the presence of WO3 had an undesired effect on the whisker morphology. A decrease in the length of mullite whisker was observed with increasing WO3 content. The effect of WO3 on the mullite phase formation temperature, as well as the whisker morphology, was explained using a dissolution-precipitation mechanism. © 2003 Elsevier Ltd. All rights reserved.
Original languageEnglish
Pages (from-to)2257-2264
JournalJournal of the European Ceramic Society
Volume23
Issue number13
Online published17 Apr 2003
DOIs
Publication statusPublished - Dec 2003
Externally publishedYes

Research Keywords

  • Anisotropy
  • Grain growth
  • Milling
  • Mullite
  • Whiskers

Policy Impact

  • Cited in Policy Documents

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