Green Fabrication of Freestanding Piezoceramic Films for Energy Harvesting and Virus Detection

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review

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Detail(s)

Original languageEnglish
Article number131
Journal / PublicationNano-Micro Letters
Volume15
Issue number1
Online published20 May 2023
Publication statusPublished - Dec 2023

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Abstract

Most electronics such as sensors, actuators and energy harvesters need piezoceramic films to interconvert mechanical and electrical energy. Transferring the ceramic films from their growth substrates for assembling electronic devices commonly requires chemical or physical etching, which comes at the sacrifice of the substrate materials, film cracks, and environmental contamination. Here, we introduce a van der Waals stripping method to fabricate large-area and freestanding piezoceramic thin films in a simple, green, and cost-effective manner. The introduction of the quasi van der Waals epitaxial platinum layer enables the capillary force of water to drive the separation process of the film and substrate interface. The fabricated lead-free film, Ba0.85Ca0.15Zr0.1Ti0.9O3 (BCZT), shows a high piezoelectric coefficient d33 = 209 ± 10 pm V−1 and outstanding flexibility of maximum strain 2%. The freestanding feature enables a wide application scenario, including micro energy harvesting, and covid-19 spike protein detection. We further conduct a life cycle analysis and quantify the low energy consumption and low pollution of the water-based stripping film method. [Media Object not available: see fulltext.] 

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Research Area(s)

  • Energy harvesting, Freestanding oxide films, Van der Waals, Virus sensor, Water stripping

Bibliographic Note

Publisher Copyright: © 2023, The Author(s).

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