Frustrated Lewis pair induced boroauration of terminal alkynes

Hongyan Ye; Zhenpin Lu; Di You; Zhenxia Chen; Zhen Hua Li; Huadong Wang

doi:10.1002/anie.201206927

Frustrated Lewis pair induced boroauration of terminal alkynes

Hongyan Ye
, Zhenpin Lu
, Di You
, Zhenxia Chen
, Zhen Hua Li^*
, Huadong Wang^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

35 Citations (Scopus)

Abstract

Golden frustration: The facile activation of terminal alkynes with a frustrated Lewis pair (1 and 1,4-diazabicyclo[2.2.2]octane (DABCO)) enables the development of an efficient boroauration reaction. This process can be achieved directly from alkynes, a hydroborane, [PPh<sub>3</sub>AuCl], and an organic base. Ar^F= 2,4,6-tris(trifluoromethyl)phenyl. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Original language	English
Pages (from-to)	12047-12050
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	48
Online published	18 Oct 2012
DOIs	https://doi.org/10.1002/anie.201206927
Publication status	Published - 26 Nov 2012
Externally published	Yes

Bibliographical note

Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

Research Keywords

alkynes
boron
gold
metalation

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10.1002/anie.201206927

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title = "Frustrated Lewis pair induced boroauration of terminal alkynes",

abstract = "Golden frustration: The facile activation of terminal alkynes with a frustrated Lewis pair (1 and 1,4-diazabicyclo[2.2.2]octane (DABCO)) enables the development of an efficient boroauration reaction. This process can be achieved directly from alkynes, a hydroborane, [PPh3AuCl], and an organic base. ArF = 2,4,6-tris(trifluoromethyl)phenyl. Copyright {\textcopyright} 2012 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim.",

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TY - JOUR

T1 - Frustrated Lewis pair induced boroauration of terminal alkynes

AU - Ye, Hongyan

AU - Lu, Zhenpin

AU - You, Di

AU - Chen, Zhenxia

AU - Li, Zhen Hua

AU - Wang, Huadong

N1 - Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

PY - 2012/11/26

Y1 - 2012/11/26

N2 - Golden frustration: The facile activation of terminal alkynes with a frustrated Lewis pair (1 and 1,4-diazabicyclo[2.2.2]octane (DABCO)) enables the development of an efficient boroauration reaction. This process can be achieved directly from alkynes, a hydroborane, [PPh3AuCl], and an organic base. ArF = 2,4,6-tris(trifluoromethyl)phenyl. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

AB - Golden frustration: The facile activation of terminal alkynes with a frustrated Lewis pair (1 and 1,4-diazabicyclo[2.2.2]octane (DABCO)) enables the development of an efficient boroauration reaction. This process can be achieved directly from alkynes, a hydroborane, [PPh3AuCl], and an organic base. ArF = 2,4,6-tris(trifluoromethyl)phenyl. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

KW - alkynes

KW - boron

KW - gold

KW - metalation

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U2 - 10.1002/anie.201206927

DO - 10.1002/anie.201206927

M3 - RGC 21 - Publication in refereed journal

SN - 1433-7851

VL - 51

SP - 12047

EP - 12050

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 48

ER -

Frustrated Lewis pair induced boroauration of terminal alkynes

Abstract

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Research Keywords

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