Frustrated Lewis pair induced boroauration of terminal alkynes

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review

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Author(s)

  • Hongyan Ye
  • Di You
  • Zhenxia Chen
  • Zhen Hua Li
  • Huadong Wang

Detail(s)

Original languageEnglish
Pages (from-to)12047-12050
Journal / PublicationAngewandte Chemie - International Edition
Volume51
Issue number48
Online published18 Oct 2012
Publication statusPublished - 26 Nov 2012
Externally publishedYes

Abstract

Golden frustration: The facile activation of terminal alkynes with a frustrated Lewis pair (1 and 1,4-diazabicyclo[2.2.2]octane (DABCO)) enables the development of an efficient boroauration reaction. This process can be achieved directly from alkynes, a hydroborane, [PPh<sub>3</sub>AuCl], and an organic base. ArF = 2,4,6-tris(trifluoromethyl)phenyl. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Research Area(s)

  • alkynes, boron, gold, metalation

Bibliographic Note

Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to lbscholars@cityu.edu.hk.

Citation Format(s)

Frustrated Lewis pair induced boroauration of terminal alkynes. / Ye, Hongyan; Lu, Zhenpin; You, Di et al.

In: Angewandte Chemie - International Edition, Vol. 51, No. 48, 26.11.2012, p. 12047-12050.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review