Freeze/thaw treatment of oily sludge from petroleum refinery plant

D. S. Jean, C. P. Chu, D. J. Lee

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

37 Citations (Scopus)

Abstract

A petroleum refinery plant in Taiwan generates approximately 2.8 × 104 tons of oily sludge, including the residual from storage tanks, and the scum sludge and waste-activated sludge from the wastewater treatment plant. Experimental results indicate that freezing and thawing can transform the flocs into large and compact aggregates and significantly enhance the sludge deliquorability for scum and waste-activated sludges. The results are attributed to the advance of an ice front during freezing that expels oil phases from the sludge body. Cationic polyelectrolyte conditioning only slightly influences sludge with a high oil content because the chemical conditioner largely binds to oily droplets on the sludge flocs. However, neither freeze/thaw treatment nor polyelectrolyte conditioning can satisfactorily condition the tank residual. Underlying mechanisms of oily sludge conditioning are discussed.
Original languageEnglish
Pages (from-to)2733-2746
JournalSeparation Science and Technology
Volume36
Issue number12
DOIs
Publication statusPublished - 30 Sept 2001
Externally publishedYes

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Research Keywords

  • Deliquoring
  • Expression
  • Freeze/thaw
  • Oily sludge
  • Polyelectrolyte

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