Formation Mechanism of Atmospheric Ammonium Bisulfate : Hydrogen-Bond-Promoted Nearly Barrierless Reactions of SO3 with NH3 and H2O

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review

8 Scopus Citations
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Author(s)

Detail(s)

Original languageEnglish
Pages (from-to)967-972
Journal / PublicationChemPhysChem
Volume19
Issue number8
Online published20 Feb 2018
Publication statusPublished - 17 Apr 2018

Abstract

Particulate matter (PM) air pollution threatens the health of people and ecosystems worldwide. As the key component of PM, ammonium sulfate plays a critical role in the formation of aerosol particles; thus, there is an urgent need to know the detailed mechanisms for its formation in the atmosphere. Through a quantum chemistry study, we reveal a series of nearly barrierless reactions that may occur in clusters/droplets in the atmosphere leading to the formation of ammonium bisulfate (NH4HSO4), the precursor of ammonium sulfate. In this mechanism, NH4HSO4 is directly formed through one-step reactions of SO3 with H2O and NH3 promoted by surrounding molecule(s) that substantially lower the reaction activation barrier to ≈0 kcal mol−1. The promoters of these reactions are found to be various common atmospheric molecules, such as water, ammonia, and sulfuric acid, which can form relatively strong hydrogen bonds with the reaction center. Our results suggest many more similar pathways that can be facilitated by other ambient molecules. Due to its one-step and barrierless reaction characteristics and the great abundance of potential reactions, this mechanism has great implications on the formation of atmospheric ammonium sulfate as well as on the growth of aerosol particles.

Research Area(s)

  • ammonia, ammonium bisulfate, formation mechanism, particulate matter, sulfur trioxide