Formation and stabilization of a decanuclear CuII wheel linked by chloride and O ··· H-N hydrogen bonds

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review

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Author(s)

  • Che-Hao Chang
  • Kuo Chu Hwang
  • Chao-Shiuan Liu
  • Arthur J. Carty
  • Ludmila Scoles
  • Shie-Ming Peng
  • Gene-Hsiang Lee
  • Jan Reedijk

Detail(s)

Original languageEnglish
Pages (from-to)4651-4653
Journal / PublicationAngewandte Chemie - International Edition
Volume40
Issue number24
Publication statusPublished - 17 Dec 2001
Externally publishedYes

Abstract

Copper gets into the ring: A decanuclear cyclic CuII complex is synthesized by direct treatment of CuCl2 with a fluorinated amino alcoholate containing one secondary and one tertiary nitrogen donor (see space-filling diagram; Cu light blue, Cl yellow, O red, N dark blue, C gray). Possible factors that lead to the self-assembly of the unique molecular wheel are discussed.

Research Area(s)

  • Copper, Hydrogen bonds, Magnetic properties, N,O ligands, Self-assembly

Citation Format(s)

Formation and stabilization of a decanuclear CuII wheel linked by chloride and O ··· H-N hydrogen bonds. / Chang, Che-Hao; Hwang, Kuo Chu; Liu, Chao-Shiuan et al.

In: Angewandte Chemie - International Edition, Vol. 40, No. 24, 17.12.2001, p. 4651-4653.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journalpeer-review