Fine-Tuning Nanoparticle Packing at Water-Oil Interfaces Using Ionic Strength

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journal

28 Scopus Citations
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Author(s)

  • Yu Chai
  • Alysia Lukito
  • Yufeng Jiang
  • Paul D. Ashby
  • Thomas P. Russell

Detail(s)

Original languageEnglish
Pages (from-to)6453-6457
Journal / PublicationNano Letters
Volume17
Issue number10
Online published15 Sep 2017
Publication statusPublished - 11 Oct 2017
Externally publishedYes

Abstract

Nanoparticle-surfactants (NPSs) assembled at water-oil interfaces can significantly lower the interfacial tension and can be used to stabilize liquids. Knowing the formation and assembly and actively tuning the packing of these NPSs is of significant fundamental interest for the interfacial behavior of nanoparticles and of interest for water purification, drug encapsulation, enhanced oil recovery, and innovative energy transduction applications. Here, we demonstrate by means of interfacial tension measurements the high ionic strength helps the adsorption of NPSs to the water-oil interface leading to a denser packing of NPSs at the interface. With the reduction of interfacial area, the phase transitions from a "gas"-like to "liquid" to "solid" states of NPSs in two dimensions are observed. Finally, we provide the first in situ real-space imaging of NPSs at the water-oil interface by atomic force microcopy.

Research Area(s)

  • in situ AFM, interfacial tension, liquid-liquid interfaces, Nanoparticles, self-assembly, surfactants

Citation Format(s)

Fine-Tuning Nanoparticle Packing at Water-Oil Interfaces Using Ionic Strength. / Chai, Yu; Lukito, Alysia; Jiang, Yufeng; Ashby, Paul D.; Russell, Thomas P.

In: Nano Letters, Vol. 17, No. 10, 11.10.2017, p. 6453-6457.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)21_Publication in refereed journal