Ferromagnetic ordering in a diamond-like cyano-bridged MnIIRuIII bimetallic coordination polymer

Wai-Fun Yeung; Wai-Lun Man; Wing-Tak Wong; Tai-Chu Lau; Song Gao

doi:10.1002/1521-3757(20010817)113:16<3121::aid-ange3121>3.0.co;2-u

Ferromagnetic ordering in a diamond-like cyano-bridged MnIIRuIII bimetallic coordination polymer

Wai-Fun Yeung
, Wai-Lun Man
, Wing-Tak Wong
, Tai-Chu Lau
, Song Gao

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

101 Citations (Scopus)

Abstract

Cyano-mediated interaction of the alternating high-spin Mn^II centers and low-spin Ru^III centers in {Mn[Ru(acac)₂(CN)₂]₂}n (Hacac = acetylacetone) results in long-range ferromagnetic ordering below 3.6 K. This novel Mn^IIRu^III coordination polymer, which has a diamond-like structure (see picture), was constructed from [Ru(acac)₂(CN)₂]- and Mn²⁺ ions.

Original language	English
Pages (from-to)	3031-3033
Journal	Angewandte Chemie - International Edition
Volume	40
Issue number	16
DOIs	https://doi.org/10.1002/1521-3757(20010817)113:16<3121::aid-ange3121>3.0.co;2-u
Publication status	Published - 17 Aug 2001

Research Keywords

Coordination polymers
Cyanides
Magnetic properties
Manganese
Ruthenium

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10.1002/1521-3757(20010817)113:16<3121::aid-ange3121>3.0.co;2-u

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title = "Ferromagnetic ordering in a diamond-like cyano-bridged MnIIRuIII bimetallic coordination polymer",

abstract = "Cyano-mediated interaction of the alternating high-spin MnII centers and low-spin RuIII centers in \{Mn[Ru(acac)2(CN)2]2\}n (Hacac = acetylacetone) results in long-range ferromagnetic ordering below 3.6 K. This novel MnIIRuIII coordination polymer, which has a diamond-like structure (see picture), was constructed from [Ru(acac)2(CN)2]- and Mn2+ ions.",

keywords = "Coordination polymers, Cyanides, Magnetic properties, Manganese, Ruthenium",

author = "Wai-Fun Yeung and Wai-Lun Man and Wing-Tak Wong and Tai-Chu Lau and Song Gao",

year = "2001",

month = aug,

day = "17",

doi = "10.1002/1521-3757(20010817)113:16<3121::aid-ange3121>3.0.co;2-u",

language = "English",

volume = "40",

pages = "3031--3033",

journal = "Angewandte Chemie - International Edition",

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publisher = "John Wiley \& Sons",

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}

TY - JOUR

T1 - Ferromagnetic ordering in a diamond-like cyano-bridged MnIIRuIII bimetallic coordination polymer

AU - Yeung, Wai-Fun

AU - Man, Wai-Lun

AU - Wong, Wing-Tak

AU - Lau, Tai-Chu

AU - Gao, Song

PY - 2001/8/17

Y1 - 2001/8/17

N2 - Cyano-mediated interaction of the alternating high-spin MnII centers and low-spin RuIII centers in {Mn[Ru(acac)2(CN)2]2}n (Hacac = acetylacetone) results in long-range ferromagnetic ordering below 3.6 K. This novel MnIIRuIII coordination polymer, which has a diamond-like structure (see picture), was constructed from [Ru(acac)2(CN)2]- and Mn2+ ions.

AB - Cyano-mediated interaction of the alternating high-spin MnII centers and low-spin RuIII centers in {Mn[Ru(acac)2(CN)2]2}n (Hacac = acetylacetone) results in long-range ferromagnetic ordering below 3.6 K. This novel MnIIRuIII coordination polymer, which has a diamond-like structure (see picture), was constructed from [Ru(acac)2(CN)2]- and Mn2+ ions.

KW - Coordination polymers

KW - Cyanides

KW - Magnetic properties

KW - Manganese

KW - Ruthenium

UR - https://www.scopus.com/pages/publications/0035902872

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-0035902872&origin=recordpage

U2 - 10.1002/1521-3757(20010817)113:16<3121::aid-ange3121>3.0.co;2-u

DO - 10.1002/1521-3757(20010817)113:16<3121::aid-ange3121>3.0.co;2-u

M3 - RGC 21 - Publication in refereed journal

SN - 1433-7851

VL - 40

SP - 3031

EP - 3033

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 16

ER -

Ferromagnetic ordering in a diamond-like cyano-bridged MnIIRuIII bimetallic coordination polymer

Abstract

Research Keywords

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