Ferrocene-based metal-organic framework as a promising cathode in lithium-ion battery
Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
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Detail(s)
Original language | English |
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Article number | 126463 |
Journal / Publication | Chemical Engineering Journal |
Volume | 404 |
Online published | 30 Jul 2020 |
Publication status | Published - 15 Jan 2021 |
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Abstract
Here, a ferrocene-based metal–organic framework, Iron (III) 1,1′-Ferrocenedicarboxylate (Fe2(DFc)3), was successfully synthesized and employed as an efficient and stable cathode for lithium-ion battery (LIB). Benefiting from its unique structure and low solubility as well as the reversible redox shuttle of Fe2+/Fe3+, LIBs with Fe2(DFc)3 as cathodes showed a high energy density of 549 Wh kg−1 (vs. lithium anode) and superior electrochemical performance including the relatively high operation potential of 3.55 V (vs. Li+/Li), the high specific capacity of 172 mAh g−1 at 50 mA g−1, and the high average specific capacity of 70 mAh g−1 at the current density of 2000 mA g−1 for 10,000 cycles.
Research Area(s)
- Cathode, Ferrocene, High performance, Lithium-ion battery, Metal-organic framework
Citation Format(s)
Ferrocene-based metal-organic framework as a promising cathode in lithium-ion battery. / Li, Chao; Zhang, Cheng; Xie, Jian; Wang, Kuaibing; Li, Jingze; Zhang, Qichun.
In: Chemical Engineering Journal, Vol. 404, 126463, 15.01.2021.Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review