Facile interconversion of terminal, doubly bridging, and quadruply bridging carbonyl ligands in solution : Crystal structure and solution dynamics of the complexes LWRu3(CO)12H, L = C5H5 and C5Me5

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

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Author(s)

  • Yun Chi
  • Fang-Jy Wu
  • Bang-Ji Liu
  • Chwan-Chin Wang
  • Sue-Lein Wang

Detail(s)

Original languageEnglish
Pages (from-to)873-875
Journal / PublicationJournal of the Chemical Society, Chemical Communications
Issue number13
Publication statusPublished - 1989
Externally publishedYes

Link(s)

DOI

DOI
Check@CityULib
Link to Scopus https://www.scopus.com/record/display.uri?eid=2-s2.0-37049078957&origin=recordpage
Permanent Link https://scholars.cityu.edu.hk/en/publications/publication(a230dd29-1487-4664-bba7-487557852988).html

Abstract

The crystal structures of the tetranuclear mixed-metal complexes LWRu 3(CO)12H, L=C5H5 and C 5Me5, were determined, indicating the presence of a butterfly arrangement with an unusual μ4-η2-CO ligand; in solution, these isomers are in equilibrium with other isomers containing only normal σ-bonded CO ligands.

Citation Format(s)

[ RIS ] [ BibTeX ]

Facile interconversion of terminal, doubly bridging, and quadruply bridging carbonyl ligands in solution : Crystal structure and solution dynamics of the complexes LWRu3(CO)12H, L = C5H5 and C5Me5. / Chi, Yun; Wu, Fang-Jy; Liu, Bang-Ji et al.

In: Journal of the Chemical Society, Chemical Communications, No. 13, 1989, p. 873-875.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review