Experiment and theory reveal the fundamental difference between two-state and single-state reactivity patterns in nonheme FeIV=O versus Ru IV=O oxidants

Sunder N. Dhuri; Sook Seo Mi; Yong-Min Lee; Hajime Hirao; Yong Wang; Wonwoo Nam; Sason Shaik

doi:10.1002/anie.200705880

Author(s)

Sunder N. Dhuri
Sook Seo Mi
Yong-Min Lee
Yong Wang
Wonwoo Nam
Sason Shaik

Detail(s)

Original language	English
Pages (from-to)	3356-3359
Journal / Publication	Angewandte Chemie - International Edition
Volume	47
Issue number	18
Publication status	Published - 21 Apr 2008
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1002/anie.200705880 Final Published version
	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-43849098402&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(c01dddf0-60b5-4eb3-bde3-5e0574077f33).html

Abstract

(Chemical Equation Presented) Two-state reactivity involving close triplet ground and quintet excited states is responsible for the opposite reactivity trends of Fe^IV oxo complexes in O-transfer and H-abstraction reactions in dependence on the electron richness of the axial ligand X (see picture), as shown by comparison with Ru^IV analogues, in which both reactivities are solely governed by the electrophilicity of the complex because the quintet state is inaccessible. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

Research Area(s)

Bioinorganic chemistry, Iron, Oxo ligands, Reaction mechanisms, Ruthenium

Citation Format(s)

[ RIS ] [ BibTeX ]

Experiment and theory reveal the fundamental difference between two-state and single-state reactivity patterns in nonheme Fe^IV=O versus Ru ^IV=O oxidants. / Dhuri, Sunder N.; Mi, Sook Seo; Lee, Yong-Min et al.

In: Angewandte Chemie - International Edition, Vol. 47, No. 18, 21.04.2008, p. 3356-3359.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

Dhuri, SN, Mi, SS, Lee, Y-M, Hirao, H, Wang, Y, Nam, W & Shaik, S 2008, 'Experiment and theory reveal the fundamental difference between two-state and single-state reactivity patterns in nonheme Fe^IV=O versus Ru ^IV=O oxidants', Angewandte Chemie - International Edition, vol. 47, no. 18, pp. 3356-3359. https://doi.org/10.1002/anie.200705880

Dhuri, S. N., Mi, S. S., Lee, Y-M., Hirao, H., Wang, Y., Nam, W., & Shaik, S. (2008). Experiment and theory reveal the fundamental difference between two-state and single-state reactivity patterns in nonheme Fe^IV=O versus Ru ^IV=O oxidants. Angewandte Chemie - International Edition, 47(18), 3356-3359. https://doi.org/10.1002/anie.200705880

Dhuri SN, Mi SS, Lee Y-M, Hirao H, Wang Y, Nam W et al. Experiment and theory reveal the fundamental difference between two-state and single-state reactivity patterns in nonheme Fe^IV=O versus Ru ^IV=O oxidants. Angewandte Chemie - International Edition. 2008 Apr 21;47(18):3356-3359. doi: 10.1002/anie.200705880

Dhuri, Sunder N. ; Mi, Sook Seo ; Lee, Yong-Min et al. / Experiment and theory reveal the fundamental difference between two-state and single-state reactivity patterns in nonheme Fe^IV=O versus Ru ^IV=O oxidants. In: Angewandte Chemie - International Edition. 2008 ; Vol. 47, No. 18. pp. 3356-3359.