Exceptional high-temperature oxidation resistance and mechanisms of a novel chemically complex intermetallic alloy

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

7 Scopus Citations
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Author(s)

  • Jinxiong Hou
  • Hongzhou Tian
  • Jiang Ju
  • Yinghao Zhou
  • Hongwei Yao
  • Zhenghao Chen

Detail(s)

Original languageEnglish
Article number111607
Journal / PublicationCorrosion Science
Volume225
Online published16 Oct 2023
Publication statusPublished - Dec 2023

Abstract

A novel chemically complex intermetallic alloy (CCIMA) dominated with an ordered L12 structure was designed based on the multicomponent Ni-Co-Cr-Al-Mo-Ti-Ta-Nb-B system. Its oxidation behaviors and underlying mechanisms were systematically investigated. Oxidation at 900 ℃ and 1000 ℃ results in the formation of main multicomponent spinel oxides in the outmost layer, spinel oxides containing rutile-type oxides and boron oxides in the intermediate layer, and continuous Al2O3 in the inner layer. Furthermore, oxidation leads to phase transformation from L12 to D024 at the matrix/oxide layer interface due to Al-depletion. The continuously formed inner Al2O3 oxides have well protected the alloy from oxidizing. © 2023 Elsevier Ltd. All rights reserved.

Research Area(s)

  • Intermetallic alloys, Microstructures, Oxidation mechanisms, Oxidation resistance