Abstract
YCa4O(BO3)3 (YCOB) and GdCa4O(BO3)3 (GdCOB) crystals are promising piezoelectric materials for high-temperature sensing applications. The high-temperature condition is accompanied by hard irradiation, such as in a nuclear power plant. In this study, the electroelastic properties of YCOB and GdCOB crystals irradiated by different doses of 6 MeV Xe23+ (1013, 1015, and 1016 ions/cm2) were studied in the temperature range of 25-850 °C. YCOB and GdCOB crystals exhibit good electrical resistivity stability with irradiation, where the resistivity of >108 Ω·cm is achieved @700 °C. Meanwhile, the electroelastic properties are found to maintain similar values, with variations being less than 8% after irradiation. The band gaps of the YCOB and GdCOB crystals are narrowed upon irradiation, leading to a slight decrease in electrical resistivity, while the slight increase in the dielectric permittivity after irradiation is associated with the irradiation-induced distortion of the structure and weakening of chemical bonding. All the irradiation resistant properties demonstrate that the bulk YCOB and GdCOB crystals are good candidates for use in high-temperature piezoelectric sensing under harsh environments including hard irradiation. © 2020 American Chemical Society.
| Original language | English |
|---|---|
| Pages (from-to) | 2651-2659 |
| Journal | Crystal Growth & Design |
| Volume | 20 |
| Issue number | 4 |
| Online published | 5 Mar 2020 |
| DOIs | |
| Publication status | Published - 1 Apr 2020 |
| Externally published | Yes |
Funding
This work was supported by The Key Research and Development Program of Shandong Province (Nos. 2017CXGC0413 and 2019JZZY010313), the National Natural Science Foundation of China (No. 51872165), and the Natural Science Foundation of Shandong Province, China (No. ZR2018BF029).
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