Equilibrium partial pressures of strong acids over concentrated solutions-III. The temperature variation of HNO3 solubility

Research output: Journal Publications and Reviews (RGC: 21, 22, 62)22_Publication in policy or professional journal

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Author(s)

  • Peter Brimblecombe
  • Simon L Clegg

Detail(s)

Original languageEnglish
Pages (from-to)1945-1955
Journal / PublicationAtmospheric Environment Part A, General Topics
Volume24
Issue number7
Publication statusPublished - 1990
Externally publishedYes

Abstract

The mole fraction Henry's Law constant (KHx/atm-1) of nitric acid is described by the equation KHx = xH+ · xNO3 - · f± */pHNO3, where f± * is the mean rational activity coefficient, prefix 'x' indicates mole fraction (calculated on the basis of complete dissociation in solution), and 'p' denotes partial pressure. From 215Hx) is given by: 385.972199-3020.3522/T - 71.001998 ln T + 0.131442311 T - 0.420928363 × 10-4 T2. The mean activity coefficient of pure aqueous HNO3 is described from 0 to 100% HNO3 by an empirical extension to the Pitzer and Simonson thermodynamic model, allowing activities of both HNO3 and H2O to be easily calculated. This approach, in addition to its utility at normal and high temperatures, offers a considerable improvement over the methods previously used for estimating the partial pressure of HNO3 over the low temperature, highly concentrated aerosols found in the stratosphere. © 1990.

Research Area(s)

  • activity coefficients, Henry's Law, Nitric acid, Pitzer and Simonson model, stratospheric aerosol, temperature effects

Citation Format(s)