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Enhanced ferroelectric photoelectrochemical properties of polycrystalline BiFeO3 film by decorating with Ag nanoparticles

  • Qing Liu
  • , Yang Zhou
  • , Lu You
  • , Junling Wang
  • , Mingrong Shen
  • , Liang Fang*
  • *Corresponding author for this work

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

Abstract

Polycrystalline BiFeO3 (BFO) films are fabricated on Pt/Ti/SiO2/Si(100) substrate as photoelectrode using sol-gel method. The microstructure, optical, and photoelectrochemical (PEC) properties of the films are characterized and optimized by controlling the film thickness. Moreover, the PEC properties of the BFO films are dependent on ferroelectric polarization, which is mainly ascribed to the modulation of band structure at the BFO/electrolyte interface by the polarization. Further enhancement of PEC properties is obtained by decorating the samples with appropriate amounts of Ag nanoparticles, which is attributed to the reduced electron-hole recombination, and localized surface plasmon resonance effect of Ag nanoparticles. © 2016 AIP Publishing LLC.
Original languageEnglish
Article number022902
JournalApplied Physics Letters
Volume108
Issue number2
DOIs
Publication statusPublished - 11 Jan 2016
Externally publishedYes

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