Engineering of Single-Atomic Sites for Electro- and Photo-Catalytic H2O2 Production

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

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Original languageEnglish
Article number2412386
Journal / PublicationAdvanced Materials
Publication statusOnline published - 25 Oct 2024

Abstract

Direct electro- and photo-synthesis of H2O2 through the 2e O2 reduction reaction (ORR) and H2O oxidation reaction (WOR) offer promising alternatives for on-demand and on-site production of this chemical. Exploring robust and selective active sites is crucial for enhancing H2O2 production through these pathways. Single-atom catalysts (SACs), featuring isolated active sites on supports, possess attractive properties for promoting catalysis and unraveling catalytic mechanisms. This review first systematically summarizes significant advancements in atomic engineering of both metal and nonmetal single-atom sites for electro- and photo-catalytic 2e ORR to H2O2, as well as the dynamic behaviors of active sites during catalytic processes. Next, the progress of single-atom sites in H2O2 production through 2e WOR is overviewed. The effects of the local physicochemical environments on the electronic structures and catalytic behaviors of isolated sites, along with the atomic catalytic mechanism involved in these H2O2 production pathways, are discussed in detail. This work also discusses the recent applications of H2O2 in advanced chemical transformations. Finally, a perspective on the development of single-atom catalysis is highlighted, aiming to provide insights into future research on SACs for electro- and photo-synthesis of H2O2 and other advanced catalytic applications. © 2024 Wiley-VCH GmbH.

Research Area(s)

  • electrocatalysis, H2O2 production, O2 reduction, photocatalysis, single-atom catalysts