Engineering channels of metal-organic frameworks to enhance catalytic selectivity

Ye Liu; Yu Shen; Weina Zhang; Jiena Weng; Meiting Zhao; Tingshun Zhu; Yonggui Robin Chi; Yanhui Yang; Hua Zhang; Fengwei Huo

doi:10.1039/c9cc06061h

Author(s)

Ye Liu
Yu Shen
Weina Zhang
Jiena Weng
Meiting Zhao
Tingshun Zhu
Yonggui Robin Chi
Yanhui Yang
Fengwei Huo

Related Research Unit(s)

Department of Chemistry

Detail(s)

Original language	English
Pages (from-to)	11770-11773
Journal / Publication	Chemical Communications
Volume	55
Issue number	78
Online published	7 Sept 2019
Publication status	Published - 7 Oct 2019

Link(s)

DOI	DOI https://doi.org/10.1039/c9cc06061h Final Published version
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Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-85072686923&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(f0ee444c-b1e7-468f-a881-8c5f00fdee85).html

Abstract

This report describes a facile strategy to enhance the catalytic selectivity by tuning the pore sizes of metal-organic frameworks (MOFs) in nanoparticles (NPs)/MOF composite catalysts. A general post-synthetic modification method was used to adjust the pore sizes of MOFs by using anhydrides with different chain lengths to react with amino groups in the ligands. The modified NPs/MOF catalysts exhibited enhanced size selectivity performance in the hydrogenation of olefins, which revealed the flexibility of MOFs as supporting materials for heterogeneous catalysis.

Research Area(s)

AT-MOF, IMPARTING FUNCTIONALITY, PD NANOPARTICLES, CO OXIDATION, SIZE, STORAGE

Citation Format(s)

[ RIS ] [ BibTeX ]

Engineering channels of metal-organic frameworks to enhance catalytic selectivity. / Liu, Ye; Shen, Yu; Zhang, Weina et al.
In: Chemical Communications, Vol. 55, No. 78, 07.10.2019, p. 11770-11773.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

Liu, Y, Shen, Y, Zhang, W, Weng, J, Zhao, M, Zhu, T, Chi, YR, Yang, Y, Zhang, H & Huo, F 2019, 'Engineering channels of metal-organic frameworks to enhance catalytic selectivity', Chemical Communications, vol. 55, no. 78, pp. 11770-11773. https://doi.org/10.1039/c9cc06061h

Liu, Y., Shen, Y., Zhang, W., Weng, J., Zhao, M., Zhu, T., Chi, Y. R., Yang, Y., Zhang, H., & Huo, F. (2019). Engineering channels of metal-organic frameworks to enhance catalytic selectivity. Chemical Communications, 55(78), 11770-11773. https://doi.org/10.1039/c9cc06061h

Liu Y, Shen Y, Zhang W, Weng J, Zhao M, Zhu T et al. Engineering channels of metal-organic frameworks to enhance catalytic selectivity. Chemical Communications. 2019 Oct 7;55(78):11770-11773. Epub 2019 Sept 7. doi: 10.1039/c9cc06061h

Liu, Ye ; Shen, Yu ; Zhang, Weina et al. / Engineering channels of metal-organic frameworks to enhance catalytic selectivity. In: Chemical Communications. 2019 ; Vol. 55, No. 78. pp. 11770-11773.