Engineering channels of metal-organic frameworks to enhance catalytic selectivity

Ye Liu; Yu Shen; Weina Zhang; Jiena Weng; Meiting Zhao; Tingshun Zhu; Yonggui Robin Chi; Yanhui Yang; Hua Zhang; Fengwei Huo

doi:10.1039/c9cc06061h

Engineering channels of metal-organic frameworks to enhance catalytic selectivity

Ye Liu
, Yu Shen
, Weina Zhang^*
, Jiena Weng
, Meiting Zhao
, Tingshun Zhu
, Yonggui Robin Chi
, Yanhui Yang
, Hua Zhang^*
, Fengwei Huo^*

^*Corresponding author for this work

Department of Chemistry

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

30 Citations (Scopus)

Abstract

This report describes a facile strategy to enhance the catalytic selectivity by tuning the pore sizes of metal-organic frameworks (MOFs) in nanoparticles (NPs)/MOF composite catalysts. A general post-synthetic modification method was used to adjust the pore sizes of MOFs by using anhydrides with different chain lengths to react with amino groups in the ligands. The modified NPs/MOF catalysts exhibited enhanced size selectivity performance in the hydrogenation of olefins, which revealed the flexibility of MOFs as supporting materials for heterogeneous catalysis.

Original language	English
Pages (from-to)	11770-11773
Journal	Chemical Communications
Volume	55
Issue number	78
Online published	7 Sept 2019
DOIs	https://doi.org/10.1039/c9cc06061h
Publication status	Published - 7 Oct 2019

Research Keywords

AT-MOF
IMPARTING FUNCTIONALITY
PD NANOPARTICLES
CO OXIDATION
SIZE
STORAGE

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title = "Engineering channels of metal-organic frameworks to enhance catalytic selectivity",

abstract = "This report describes a facile strategy to enhance the catalytic selectivity by tuning the pore sizes of metal-organic frameworks (MOFs) in nanoparticles (NPs)/MOF composite catalysts. A general post-synthetic modification method was used to adjust the pore sizes of MOFs by using anhydrides with different chain lengths to react with amino groups in the ligands. The modified NPs/MOF catalysts exhibited enhanced size selectivity performance in the hydrogenation of olefins, which revealed the flexibility of MOFs as supporting materials for heterogeneous catalysis.",

keywords = "AT-MOF, IMPARTING FUNCTIONALITY, PD NANOPARTICLES, CO OXIDATION, SIZE, STORAGE",

author = "Ye Liu and Yu Shen and Weina Zhang and Jiena Weng and Meiting Zhao and Tingshun Zhu and Chi, \{Yonggui Robin\} and Yanhui Yang and Hua Zhang and Fengwei Huo",

year = "2019",

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T1 - Engineering channels of metal-organic frameworks to enhance catalytic selectivity

AU - Liu, Ye

AU - Shen, Yu

AU - Zhang, Weina

AU - Weng, Jiena

AU - Zhao, Meiting

AU - Zhu, Tingshun

AU - Chi, Yonggui Robin

AU - Yang, Yanhui

AU - Zhang, Hua

AU - Huo, Fengwei

PY - 2019/10/7

Y1 - 2019/10/7

N2 - This report describes a facile strategy to enhance the catalytic selectivity by tuning the pore sizes of metal-organic frameworks (MOFs) in nanoparticles (NPs)/MOF composite catalysts. A general post-synthetic modification method was used to adjust the pore sizes of MOFs by using anhydrides with different chain lengths to react with amino groups in the ligands. The modified NPs/MOF catalysts exhibited enhanced size selectivity performance in the hydrogenation of olefins, which revealed the flexibility of MOFs as supporting materials for heterogeneous catalysis.

AB - This report describes a facile strategy to enhance the catalytic selectivity by tuning the pore sizes of metal-organic frameworks (MOFs) in nanoparticles (NPs)/MOF composite catalysts. A general post-synthetic modification method was used to adjust the pore sizes of MOFs by using anhydrides with different chain lengths to react with amino groups in the ligands. The modified NPs/MOF catalysts exhibited enhanced size selectivity performance in the hydrogenation of olefins, which revealed the flexibility of MOFs as supporting materials for heterogeneous catalysis.

KW - AT-MOF

KW - IMPARTING FUNCTIONALITY

KW - PD NANOPARTICLES

KW - CO OXIDATION

KW - SIZE

KW - STORAGE

UR - https://www.scopus.com/pages/publications/85072686923

UR - http://gateway.isiknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=LinksAMR&SrcApp=PARTNER_APP&DestLinkType=FullRecord&DestApp=WOS&KeyUT=000487806500023

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U2 - 10.1039/c9cc06061h

DO - 10.1039/c9cc06061h

M3 - RGC 21 - Publication in refereed journal

C2 - 31513185

SN - 1359-7345

VL - 55

SP - 11770

EP - 11773

JO - Chemical Communications

JF - Chemical Communications

IS - 78

ER -

Engineering channels of metal-organic frameworks to enhance catalytic selectivity

Abstract

Research Keywords

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