Electrospray mass spectrometry studies of purified aluminum tridecamer in 50: 50 water/methanol mixture

Ya-Fan Lin; Duu-Jong Lee

doi:10.1016/j.jtice.2010.10.009

Author(s)

Ya-Fan Lin
Duu-Jong Lee

Detail(s)

Original language	English
Pages (from-to)	604-607
Journal / Publication	Journal of the Taiwan Institute of Chemical Engineers
Volume	42
Issue number	4
Publication status	Published - Jul 2011
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1016/j.jtice.2010.10.009 Final Published version
	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-79959847774&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(7a7baab6-6b23-40f1-a667-9daff09ecf8f).html

Abstract

This study conducted electrospray ionization mass spectrometry (ESI-MS) tests on 90-95% pure aluminum tridecamer (Al₁₃) salt dissolved in a 50:50 (v/v) water/methanol mixture. The mass spectra for water/methanol mixture revealed no major characteristic peaks for Al₁₃, but showed a few series with incremental difference of 32u, 18u (or 9u), and 14u in the m/z=200-500 regime. The methanol molecule typically replaces one by one the ligated aqua ligand and adducts to the aluminum center to destruct aluminum tridecamer into smaller, singly or doubly charged polymeric species. A species network with ligand substitution and addition reactions was for the first time revealed. © 2010 Taiwan Institute of Chemical Engineers.

Research Area(s)

Al13, ESI-MS, Methanol, Speciation

Bibliographic Note

Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

Citation Format(s)

[ RIS ] [ BibTeX ]

Electrospray mass spectrometry studies of purified aluminum tridecamer in 50: 50 water/methanol mixture. / Lin, Ya-Fan; Lee, Duu-Jong.
In: Journal of the Taiwan Institute of Chemical Engineers, Vol. 42, No. 4, 07.2011, p. 604-607.

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

Lin, Y-F & Lee, D-J 2011, 'Electrospray mass spectrometry studies of purified aluminum tridecamer in 50: 50 water/methanol mixture', Journal of the Taiwan Institute of Chemical Engineers, vol. 42, no. 4, pp. 604-607. https://doi.org/10.1016/j.jtice.2010.10.009

Lin, Y.-F., & Lee, D.-J. (2011). Electrospray mass spectrometry studies of purified aluminum tridecamer in 50: 50 water/methanol mixture. Journal of the Taiwan Institute of Chemical Engineers, 42(4), 604-607. https://doi.org/10.1016/j.jtice.2010.10.009

Lin YF, Lee DJ. Electrospray mass spectrometry studies of purified aluminum tridecamer in 50: 50 water/methanol mixture. Journal of the Taiwan Institute of Chemical Engineers. 2011 Jul;42(4):604-607. doi: 10.1016/j.jtice.2010.10.009

Lin, Ya-Fan ; Lee, Duu-Jong. / Electrospray mass spectrometry studies of purified aluminum tridecamer in 50 : 50 water/methanol mixture. In: Journal of the Taiwan Institute of Chemical Engineers. 2011 ; Vol. 42, No. 4. pp. 604-607.

Electrospray mass spectrometry studies of purified aluminum tridecamer in 50 : 50 water/methanol mixture