Electrocontrolled Liquid Marbles for Rapid Miniaturized Organic Reactions

Zhou Liu, Tiyun Yang, Yuxing Huang, Yang Liu, Liucheng Chen, Libo Deng, Ho Cheung Shum, Tiantian Kong*

*Corresponding author for this work

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

64 Citations (Scopus)

Abstract

Miniaturized droplet reactors hold great promise for the development of green and sustainable chemistry. However, handling liquids with small volumes, especially viscous ones, in a convenient and loss-free manner remains a challenge. Here, by electrically controlling the coalescence and mixing of particle-coated droplets, also known as liquid marbles, an effective microreactor is demonstrated for miniaturized chemical reactions involving viscous reagents. By applying an electric voltage to marbles, the induced electromixing of marble microreactors promotes the reaction rate and the product yield. The advantages of electromixed marble reactors are manifested by a series of chemical reactions between aldehydes and 2-methylindole in viscous glycerol solution. The electrically-controlled coalescence and mixing establish liquid marbles as microreactors for rapid, efficient, and miniaturized chemical reactions. © 2019 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Original languageEnglish
Article number1901101
JournalAdvanced Functional Materials
Volume29
Issue number19
DOIs
Publication statusPublished - 9 May 2019
Externally publishedYes

Bibliographical note

Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

Research Keywords

  • droplets
  • liquid marbles
  • microreactors
  • miniaturization
  • mixing

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