Efficient one-pot synthesis of 5-hydroxymethylfurfural from functionalized microcrystalline cellulose : An alternative approach to strong acidic/basic catalysis
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review
Author(s)
Detail(s)
Original language | English |
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Article number | 142219 |
Journal / Publication | Chemical Engineering Journal |
Volume | 462 |
Online published | 2 Mar 2023 |
Publication status | Published - 15 Apr 2023 |
Externally published | Yes |
Link(s)
Abstract
Selective cellulose transformation into the 5-hydroxymethylfurfural (HMF), a versatile platform chemical, has been researched using various catalysts, while desirable efficiency remains a challenge. This study revealed an alternative conversion approach to strong acidic/basic catalysis, an efficient one-pot synthesis of HMF without external catalyst from microcrystalline cellulose (MCC), functionalized via milling and subsequent oxidation pretreatment. The outstanding HMF yield (∼55%) was obtained under moderate reaction conditions (3 h, 190 °C), demonstrating the significant impact of functionalized MCC's characteristics (e.g., reduced crystallinity index (CI), degree of polymerization (DP), and the formed –COOH) and the reaction conditions (e.g., the role of NaCl and H2O/THF ratio) for HMF synthesis. The formed –COOH group demonstrated a dual-function i) in-situ destruction of MCC's β-1,4-glycosidic linkages during pretreatment ii) catalyzing hydrolysis/dehydration reactions of carbohydrates to form HMF. Furthermore, chloride ions could selectively promote consecutive reactions. The promising findings in this study provide a greener route to produce HMF from cellulose without using acid/base catalysts through cellulose structure functionalization by green/simple methods. © 2023 Published by Elsevier B.V.
Research Area(s)
- Acid/base-free system, Cellulose functionalization, HMF, Milling-oxidation pretreatments
Citation Format(s)
Efficient one-pot synthesis of 5-hydroxymethylfurfural from functionalized microcrystalline cellulose: An alternative approach to strong acidic/basic catalysis. / Rezayan, Armin; Nie, Renfeng; Wang, Jianshe et al.
In: Chemical Engineering Journal, Vol. 462, 142219, 15.04.2023.
In: Chemical Engineering Journal, Vol. 462, 142219, 15.04.2023.
Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review