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Effect of Annealing on the Structure and Magnetic Properties of CoMnSi

  • Ronghui Kou
  • , Jianrong Gao*
  • , Yang Ren
  • , Steve M. Heald
  • , Brandon L. Fisher
  • , Cheng-Jun Sun
  • *Corresponding author for this work

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

Abstract

This paper reports a comparative study of the magnetization, magnetocaloric effects, and crystal lattices of an as-cast sample and an annealed sample of the CoMnSi compound. Magnetic measurements showed that the annealed sample has high magnetization and a doubled maximum magnetic entropy change with respect to the as-cast sample. X-ray diffraction studies determined that both samples crystallize into an orthorhombic lattice. However, there are remarkable differences in the lattice parameters and one of the nearest Mn-Mn distances between the samples. Spectroscopic measurements of the X-ray absorption near-edge structure revealed that Co-Si bonds of the annealed sample are shorter than those of the as-cast sample due to stronger p - d hybridization of Co and Si atoms, while other chemical bonds do not show any difference. It is concluded that high-temperature annealing enhances ferromagnetic interactions in the lattice of CoMnSi by chemical ordering of Co atoms.
Original languageEnglish
Article number8418727
JournalIEEE Transactions on Magnetics
Volume54
Issue number11
DOIs
Publication statusPublished - 1 Nov 2018
Externally publishedYes

Bibliographical note

Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

Research Keywords

  • CoMnSi
  • extended X-ray absorption fine structure (EXAFS)
  • magnetic materials
  • magnetocaloric effect

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