Abstract
The room temperature downconversion emission of Er3+ in the low phonon energy, low band-gap host Cs2NaErCl6 upon synchrotron radiation excitation is rationalized. Energy transfer cross-relaxation schemes are proposed following the interpretation of the vacuum ultraviolet and ultraviolet excitation and emission spectra. The highest energy emission from Er3+ occurs from the 2I11/2 multiplet term (∼40600 cm-1). The behaviour of Er3+ in Cs2NaYCl6:Er3+ is also discussed and interpreted. © 2007 Elsevier B.V. All rights reserved.
| Original language | English |
|---|---|
| Pages (from-to) | 302-306 |
| Journal | Chemical Physics Letters |
| Volume | 442 |
| Issue number | 4-6 |
| DOIs | |
| Publication status | Published - 17 Jul 2007 |
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