Abstract
The synthesis of a series of phosphine‐functionalised macrocycles, 1–6, is described. The combination of N‐and O‐sites with P‐ and S‐sites provides ligands which may bind transition or non‐transition metal ions; as a consequence, they give access to dinuclear complexes containing both a Lewis acid and a redox metallic site. Compounds 1,2 and 6 are heterodinucleating ligands capable of binding two dissimilar metals in proximity. Macrocycles 3–5 are homotopic ligands which may form homodinuclear complexes of transition metals. Copyright © 1986 Verlag GmbH & Co. KGaA, Weinheim
| Original language | English |
|---|---|
| Pages (from-to) | 580-586 |
| Journal | Helvetica Chimica Acta |
| Volume | 69 |
| Issue number | 3 |
| DOIs | |
| Publication status | Published - 7 May 1986 |
| Externally published | Yes |
Bibliographical note
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