Dissolution of Intermetallic Second-Phase Particles in Zircaloy-2 in High-Temperature Steam

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

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Author(s)

  • Weicheng Zhong
  • Xiang Liu
  • Peter A. Mouche
  • Jun-Li Lin
  • Donghee Park
  • Mohamed S. Elbakhshwan
  • Simerjeet K. Gill
  • James F. Stubbins
  • Brent J. Heuser

Detail(s)

Original languageEnglish
Pages (from-to)1851-1861
Journal / PublicationMetallurgical and Materials Transactions A: Physical Metallurgy and Materials Science
Volume50
Issue number4
Publication statusPublished - 15 Apr 2019
Externally publishedYes

Abstract

The stability of intermetallic second-phase particles (SPPs) in coated Zircaloy-2 was studied in 700 °C steam environments up to 20 hours. Hydrogen generated from high-temperature steam oxidation of uncoated Zr-induced δ-hydrides formation in the Zircaloy matrix. Synchrotron XRD demonstrated that longer exposure times increased hydride peak intensity and decreased intermetallic SPPs’ peak intensity. Cross-sectional SEM analysis verified the intermetallic SPPs’ volume fraction reduction. The size distribution of intermetallic SPPs was characterized and larger particles were dissolved at longer oxidation time. A correlation between the hydrogen concentration and the volume fraction of intermetallic SPPs at 700 °C steam environment was found, with the volume fraction of SPPs decreasing as hydrogen concentration increases.

Bibliographic Note

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Citation Format(s)

Dissolution of Intermetallic Second-Phase Particles in Zircaloy-2 in High-Temperature Steam. / Zhong, Weicheng; Liu, Xiang; Mouche, Peter A. et al.
In: Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science, Vol. 50, No. 4, 15.04.2019, p. 1851-1861.

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review