Development of a novel secondary phosphine oxide-ruthenium(II) catalyst and its application for carbonyl reduction

Xuefeng Tan; Weijun Zeng; Xiaoyong Zhang; Lung Wa Chung; Xumu Zhang

doi:10.1039/c7cc07647a

Development of a novel secondary phosphine oxide-ruthenium(II) catalyst and its application for carbonyl reduction

Xuefeng Tan, Weijun Zeng, Xiaoyong Zhang, Lung Wa Chung^*, Xumu Zhang

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

21 Citations (Scopus)

Abstract

A secondary phosphine oxide-phosphine mixed tridentate ligand and its ruthenium complex have been developed. This complex shows excellent catalytic activity for carbonyl reduction, especially for the reduction of α,β-unsaturated aldehydes. The turnover number and selectivity can reach up to 36500 and 99%, respectively. Control experiments and DFT calculations supported an outer-sphere mechanism during the hydrogenation reaction. © 2018 The Royal Society of Chemistry.

Original language	English
Pages (from-to)	535-538
Journal	Chemical Communications
Volume	54
Issue number	5
DOIs	https://doi.org/10.1039/c7cc07647a
Publication status	Published - 2018
Externally published	Yes

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Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

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abstract = "A secondary phosphine oxide-phosphine mixed tridentate ligand and its ruthenium complex have been developed. This complex shows excellent catalytic activity for carbonyl reduction, especially for the reduction of α,β-unsaturated aldehydes. The turnover number and selectivity can reach up to 36500 and 99%, respectively. Control experiments and DFT calculations supported an outer-sphere mechanism during the hydrogenation reaction. {\textcopyright} 2018 The Royal Society of Chemistry.",

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AU - Zeng, Weijun

AU - Zhang, Xiaoyong

AU - Chung, Lung Wa

AU - Zhang, Xumu

N1 - Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

PY - 2018

Y1 - 2018

N2 - A secondary phosphine oxide-phosphine mixed tridentate ligand and its ruthenium complex have been developed. This complex shows excellent catalytic activity for carbonyl reduction, especially for the reduction of α,β-unsaturated aldehydes. The turnover number and selectivity can reach up to 36500 and 99%, respectively. Control experiments and DFT calculations supported an outer-sphere mechanism during the hydrogenation reaction. © 2018 The Royal Society of Chemistry.

AB - A secondary phosphine oxide-phosphine mixed tridentate ligand and its ruthenium complex have been developed. This complex shows excellent catalytic activity for carbonyl reduction, especially for the reduction of α,β-unsaturated aldehydes. The turnover number and selectivity can reach up to 36500 and 99%, respectively. Control experiments and DFT calculations supported an outer-sphere mechanism during the hydrogenation reaction. © 2018 The Royal Society of Chemistry.

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EP - 538

JO - Chemical Communications

JF - Chemical Communications

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Development of a novel secondary phosphine oxide-ruthenium(II) catalyst and its application for carbonyl reduction

Abstract

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Correction: Development of a novel secondary phosphine oxide-ruthenium(ii) catalyst and its application for carbonyl reduction ((2018) 54 (535-538) DOI: 10.1039/C7CC07647A)

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