Dehydrogenation of propane on alumina supported Pt - Sn bimetal catalysts

Ningbiao Huang; Jinzhong Tian; Qiang Liu; Junru Chen; Ruixiang Li; Xianjun Li

Dehydrogenation of propane on alumina supported Pt - Sn bimetal catalysts

Ningbiao Huang
, Jinzhong Tian
, Qiang Liu
, Junru Chen
, Ruixiang Li
, Xianjun Li

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

Abstract

The comparative studies of the catalytic properties in the dehydrogenation of propane were carried out at 500-600°C and atmospheric pressure using the catalysts derived from different Pt - Sn clusters {[PtCl (SnCl₃) (PPh₃)₂], (Me₄N)₂[(PtCl₂(SnCl₃)₂] and (Me4N)3[Pt(SnCIa)5]) and the conventional Pt - Sn catalysts prepared from H₂PtCl₆ and SnCl₂ with different Sn/Pt ratios (Sn/Pt = 1 : 1,2 : 1, 5 : 1), The results showed that Sn introduced in the catalysts inhibited the hydrocracking activities, but increased the dehydrogenation activities of propane. Moreover, the higher the content of Sn was in the catalyst (in the range of Sn/Pt ratio 1 to 5), the lower the hydrocracking activities were exhibited. Comparing two types of Pt - Sn catalysts, it is obvious that the activities, selectivities to propene and the stabilities of catalysts derived from Pt - Sn clusters, except the catalyst prepared from [PtCl (SnCl₃) (PPh₃)₂], were higher than that of the conventional Pt - Sn catalysts. This suggested that Sn in the catalysts derived from Pt - Sn clusters exhibited stronger modification for the catalytic properties of Pt and was more favourable for the Pt dispersion on a-lumina surface. Therefore, the coking and sintering on the catalyst surface were greatly decreased.

Original language	English
Pages (from-to)	112-113
Journal	Journal of Fuel Chemistry and Technology
Volume	24
Issue number	2
Publication status	Published - 1996
Externally published	Yes

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Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

Research Keywords

Dehydrogenation
Propane
Pt - Sn clusters catalyst

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@article{418d3acb0f144222881fca92eecdb8b6,

title = "Dehydrogenation of propane on alumina supported Pt - Sn bimetal catalysts",

abstract = "The comparative studies of the catalytic properties in the dehydrogenation of propane were carried out at 500-600°C and atmospheric pressure using the catalysts derived from different Pt - Sn clusters \{[PtCl (SnCl3) (PPh3)2], (Me4N)2[(PtCl2(SnCl3)2] and (Me4N)3[Pt(SnCIa)5]) and the conventional Pt - Sn catalysts prepared from H2PtCl6 and SnCl2 with different Sn/Pt ratios (Sn/Pt = 1 : 1,2 : 1, 5 : 1), The results showed that Sn introduced in the catalysts inhibited the hydrocracking activities, but increased the dehydrogenation activities of propane. Moreover, the higher the content of Sn was in the catalyst (in the range of Sn/Pt ratio 1 to 5), the lower the hydrocracking activities were exhibited. Comparing two types of Pt - Sn catalysts, it is obvious that the activities, selectivities to propene and the stabilities of catalysts derived from Pt - Sn clusters, except the catalyst prepared from [PtCl (SnCl3) (PPh3)2], were higher than that of the conventional Pt - Sn catalysts. This suggested that Sn in the catalysts derived from Pt - Sn clusters exhibited stronger modification for the catalytic properties of Pt and was more favourable for the Pt dispersion on a-lumina surface. Therefore, the coking and sintering on the catalyst surface were greatly decreased.",

keywords = "Dehydrogenation, Propane, Pt - Sn clusters catalyst",

author = "Ningbiao Huang and Jinzhong Tian and Qiang Liu and Junru Chen and Ruixiang Li and Xianjun Li",

note = "Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].",

year = "1996",

language = "English",

volume = "24",

pages = "112--113",

journal = "Journal of Fuel Chemistry and Technology",

issn = "0253-2409",

publisher = "中国科技出版传媒股份有限公司",

number = "2",

}

TY - JOUR

T1 - Dehydrogenation of propane on alumina supported Pt - Sn bimetal catalysts

AU - Huang, Ningbiao

AU - Tian, Jinzhong

AU - Liu, Qiang

AU - Chen, Junru

AU - Li, Ruixiang

AU - Li, Xianjun

N1 - Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

PY - 1996

Y1 - 1996

N2 - The comparative studies of the catalytic properties in the dehydrogenation of propane were carried out at 500-600°C and atmospheric pressure using the catalysts derived from different Pt - Sn clusters {[PtCl (SnCl3) (PPh3)2], (Me4N)2[(PtCl2(SnCl3)2] and (Me4N)3[Pt(SnCIa)5]) and the conventional Pt - Sn catalysts prepared from H2PtCl6 and SnCl2 with different Sn/Pt ratios (Sn/Pt = 1 : 1,2 : 1, 5 : 1), The results showed that Sn introduced in the catalysts inhibited the hydrocracking activities, but increased the dehydrogenation activities of propane. Moreover, the higher the content of Sn was in the catalyst (in the range of Sn/Pt ratio 1 to 5), the lower the hydrocracking activities were exhibited. Comparing two types of Pt - Sn catalysts, it is obvious that the activities, selectivities to propene and the stabilities of catalysts derived from Pt - Sn clusters, except the catalyst prepared from [PtCl (SnCl3) (PPh3)2], were higher than that of the conventional Pt - Sn catalysts. This suggested that Sn in the catalysts derived from Pt - Sn clusters exhibited stronger modification for the catalytic properties of Pt and was more favourable for the Pt dispersion on a-lumina surface. Therefore, the coking and sintering on the catalyst surface were greatly decreased.

AB - The comparative studies of the catalytic properties in the dehydrogenation of propane were carried out at 500-600°C and atmospheric pressure using the catalysts derived from different Pt - Sn clusters {[PtCl (SnCl3) (PPh3)2], (Me4N)2[(PtCl2(SnCl3)2] and (Me4N)3[Pt(SnCIa)5]) and the conventional Pt - Sn catalysts prepared from H2PtCl6 and SnCl2 with different Sn/Pt ratios (Sn/Pt = 1 : 1,2 : 1, 5 : 1), The results showed that Sn introduced in the catalysts inhibited the hydrocracking activities, but increased the dehydrogenation activities of propane. Moreover, the higher the content of Sn was in the catalyst (in the range of Sn/Pt ratio 1 to 5), the lower the hydrocracking activities were exhibited. Comparing two types of Pt - Sn catalysts, it is obvious that the activities, selectivities to propene and the stabilities of catalysts derived from Pt - Sn clusters, except the catalyst prepared from [PtCl (SnCl3) (PPh3)2], were higher than that of the conventional Pt - Sn catalysts. This suggested that Sn in the catalysts derived from Pt - Sn clusters exhibited stronger modification for the catalytic properties of Pt and was more favourable for the Pt dispersion on a-lumina surface. Therefore, the coking and sintering on the catalyst surface were greatly decreased.

KW - Dehydrogenation

KW - Propane

KW - Pt - Sn clusters catalyst

UR - https://www.scopus.com/pages/publications/8844254786

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-8844254786&origin=recordpage

M3 - RGC 21 - Publication in refereed journal

SN - 0253-2409

VL - 24

SP - 112

EP - 113

JO - Journal of Fuel Chemistry and Technology

JF - Journal of Fuel Chemistry and Technology

IS - 2

ER -

Dehydrogenation of propane on alumina supported Pt - Sn bimetal catalysts

Abstract

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Research Keywords

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