Core-shell structure and stability of nanocrystalline precipitates in Fe_83.3Si₄B₈P₄Cu_0.7 soft magnetic amorphous alloy

The core-shell nanostructure of α-Fe precipitates was investigated in a recently developed high-performance Fe_83.3Si₄B₈P₄Cu_0.7 nanocrystalline soft magnetic alloy utilizing small-angle neutron scattering (SANS) and atom probe tomography (APT). SANS measurements under a saturating magnetic field provided evidence of core-shell structures at the nanoscale. Moreover, the core-shell structure was directly visualized from APT analysis, where P-enriched shells were found around Fe-enriched cores due to the large negative heat of mixing between Fe and P elements and the slow diffusion of P atoms. The core-shell nanostructures induced by nanoscale partitioning are effective in stabilizing the residual amorphous matrix and suppressing the crystal growth. Our findings provide insight into the microstructure of Fe-based amorphous alloys and have direct implications in alloy design for the improvement of the soft magnetic properties. © 2023 Elsevier Ltd.