Copper‐Catalyzed Asymmetric Arylation of N‐Heteroaryl Aldimines : Elementary Step of a 1,4‐Insertion
Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
Author(s)
Related Research Unit(s)
Detail(s)
| Original language | English |
|---|---|
| Pages (from-to) | 2731-2735 |
| Journal / Publication | Angewandte Chemie |
| Volume | 131 |
| Issue number | 9 |
| Online published | 15 Jan 2019 |
| Publication status | Published - 25 Feb 2019 |
Link(s)
| DOI | DOI |
|---|---|
| Permanent Link | https://scholars.cityu.edu.hk/en/publications/publication(a480823d-8240-42dc-90a4-6457d875ddcc).html |
Abstract
Copper complexes of monodentate phosphoramidites efficiently promote asymmetric arylation of N‐azaaryl aldimines with arylboroxines. DFT calculations and experiments support an elementary step of 1,4‐insertion in the reaction pathway, a step in which an aryl‐copper species adds directly across four atoms of C=N−C=N in the N‐azaaryl aldimines.
Citation Format(s)
Copper‐Catalyzed Asymmetric Arylation of N‐Heteroaryl Aldimines : Elementary Step of a 1,4‐Insertion. / Wu, Chunlin; Qin, Xurong; Moeljadi, Adhitya Mangala Putra et al.
In: Angewandte Chemie, Vol. 131, No. 9, 25.02.2019, p. 2731-2735.Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
