Copper‐Catalyzed Asymmetric Arylation of N‐Heteroaryl Aldimines : Elementary Step of a 1,4‐Insertion
Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
Author(s)
Related Research Unit(s)
Detail(s)
| Original language | English |
|---|---|
| Pages (from-to) | 2705-2709 |
| Journal / Publication | Angewandte Chemie - International Edition |
| Volume | 58 |
| Issue number | 9 |
| Online published | 15 Jan 2019 |
| Publication status | Published - 25 Feb 2019 |
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Abstract
Copper complexes of monodentate phosphoramidites efficiently promote asymmetric arylation of N-azaaryl aldimines with arylboroxines. DFT calculations and experiments support an elementary step of 1,4-insertion in the reaction pathway, a step in which an aryl-copper species adds directly across four atoms of C=N−C=N in the N-azaaryl aldimines.
Research Area(s)
- 1,4-insertion, arylation, asymmetric catalysis, copper catalysis, phosphoramidate
Citation Format(s)
Copper‐Catalyzed Asymmetric Arylation of N‐Heteroaryl Aldimines : Elementary Step of a 1,4‐Insertion. / Wu, Chunlin; Qin, Xurong; Moeljadi, Adhitya Mangala Putra et al.
In: Angewandte Chemie - International Edition, Vol. 58, No. 9, 25.02.2019, p. 2705-2709.Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
