Copper-catalyzed additions of sulfonyl iodides to simple and cyclic alkenes

Lilian Kao Liu; Y. Chi; Kwan-Yue Jen

doi:10.1021/jo01291a006

Copper-catalyzed additions of sulfonyl iodides to simple and cyclic alkenes

Lilian Kao Liu, Y. Chi, Kwan-Yue Jen

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

132 Citations (Scopus)

Abstract

A convenient synthesis for various β-iodo sulfones has been developed. The reaction involves additions of alkane- and arenesulfonyl iodides to simple and cyclic alkenes under the catalytic action of copper(II) chloride. The favored stereochemical results for cyclic alkenes have been rationalized in terms of stepwise addition of both portions of the addend from the diaxial direction. © 1980 American Chemical Society.

Original language	English
Pages (from-to)	406-410
Journal	Journal of Organic Chemistry
Volume	45
Issue number	3
DOIs	https://doi.org/10.1021/jo01291a006
Publication status	Published - 1980
Externally published	Yes

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title = "Copper-catalyzed additions of sulfonyl iodides to simple and cyclic alkenes",

abstract = "A convenient synthesis for various β-iodo sulfones has been developed. The reaction involves additions of alkane- and arenesulfonyl iodides to simple and cyclic alkenes under the catalytic action of copper(II) chloride. The favored stereochemical results for cyclic alkenes have been rationalized in terms of stepwise addition of both portions of the addend from the diaxial direction. {\textcopyright} 1980 American Chemical Society.",

author = "Liu, {Lilian Kao} and Y. Chi and Kwan-Yue Jen",

year = "1980",

doi = "10.1021/jo01291a006",

language = "English",

volume = "45",

pages = "406--410",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "3",

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TY - JOUR

T1 - Copper-catalyzed additions of sulfonyl iodides to simple and cyclic alkenes

AU - Liu, Lilian Kao

AU - Chi, Y.

AU - Jen, Kwan-Yue

PY - 1980

Y1 - 1980

N2 - A convenient synthesis for various β-iodo sulfones has been developed. The reaction involves additions of alkane- and arenesulfonyl iodides to simple and cyclic alkenes under the catalytic action of copper(II) chloride. The favored stereochemical results for cyclic alkenes have been rationalized in terms of stepwise addition of both portions of the addend from the diaxial direction. © 1980 American Chemical Society.

AB - A convenient synthesis for various β-iodo sulfones has been developed. The reaction involves additions of alkane- and arenesulfonyl iodides to simple and cyclic alkenes under the catalytic action of copper(II) chloride. The favored stereochemical results for cyclic alkenes have been rationalized in terms of stepwise addition of both portions of the addend from the diaxial direction. © 1980 American Chemical Society.

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UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-0000196929&origin=recordpage

U2 - 10.1021/jo01291a006

DO - 10.1021/jo01291a006

M3 - RGC 21 - Publication in refereed journal

SN - 0022-3263

VL - 45

SP - 406

EP - 410

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 3

ER -

Copper-catalyzed additions of sulfonyl iodides to simple and cyclic alkenes

Abstract

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