TY - JOUR
T1 - Coordination polymers constructed from [Mn(N)(CN)4] 2-
T2 - Synthesis, structures, and magnetic properties
AU - Guo, Jun-Fang
AU - Yeung, Wai-Fun
AU - Gao, Song
AU - Lee, Gene-Hsiang
AU - Peng, Shie-Ming
AU - Lam, Michael Hon-Wah
AU - Lau, Tai-Chu
PY - 2008
Y1 - 2008
N2 - The dimetallic complexes [{Ni(cyclen)}(Mn(N)(CN)4· CH3OH]n (cyclen = 1,4,7,10-tetraazacyclododecane) (1), [{Cu(cyclen)}{Mn(N)(CN)4)]n (2), and [{Mn(5,5′- Me2salen))2-{Mn(N)(CN)4}·CH 3OH]n [5,5′-Me2salen = N,N′-bis(5,5′-dimethylsahcylidene)-o-ethylenediimine] (3) have been synthesized and structurally characterized. Compounds 1 and 2 have one-dimensional chain structures, while compound 3 has a two-dimensional sheet-like network structure. Magnetic studies of 1 and 3 show that there is no significant magnetic coupling between the paramagnetic metal centers. © Wiley-VCH Verlag GmbH & Co. KGaA, 2008.
AB - The dimetallic complexes [{Ni(cyclen)}(Mn(N)(CN)4· CH3OH]n (cyclen = 1,4,7,10-tetraazacyclododecane) (1), [{Cu(cyclen)}{Mn(N)(CN)4)]n (2), and [{Mn(5,5′- Me2salen))2-{Mn(N)(CN)4}·CH 3OH]n [5,5′-Me2salen = N,N′-bis(5,5′-dimethylsahcylidene)-o-ethylenediimine] (3) have been synthesized and structurally characterized. Compounds 1 and 2 have one-dimensional chain structures, while compound 3 has a two-dimensional sheet-like network structure. Magnetic studies of 1 and 3 show that there is no significant magnetic coupling between the paramagnetic metal centers. © Wiley-VCH Verlag GmbH & Co. KGaA, 2008.
KW - Coordination polymers
KW - Cyanido ligands
KW - Heterometallic complexes
KW - Magnetic properties
KW - Manganese
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U2 - 10.1002/ejic.200700807
DO - 10.1002/ejic.200700807
M3 - RGC 21 - Publication in refereed journal
SN - 1434-1948
SP - 158
EP - 163
JO - European Journal of Inorganic Chemistry
JF - European Journal of Inorganic Chemistry
IS - 1
ER -