Conventional and unconventional alkyne activations by Ru and Os for unprecedented dimetalated quinolizinium complexes
Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review
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Detail(s)
Original language | English |
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Pages (from-to) | 8908-8911 |
Journal / Publication | Chemical Communications |
Volume | 56 |
Issue number | 63 |
Online published | 10 Jul 2020 |
Publication status | Published - 14 Aug 2020 |
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Abstract
Two types of unexpected quinolizinium complexes were obtained from the reactions between pyridine-functionalized propargylic alcohol HC≡CC(OH)(Ph)(CH2(2-py)) (L1) and cis-[M(L^L)2Cl2] (M = Ru, Os; L^L = 1,1-bis(diphenylphosphino)methane (dppm), 2,2′-bipyridine (bpy)). Their molecular structures revealed that L1 can be activated by Ru and Os via the conventional "vinylidene-involving"or unconventional "non-vinylidene-involving" pathways.
Citation Format(s)
Conventional and unconventional alkyne activations by Ru and Os for unprecedented dimetalated quinolizinium complexes. / Yeung, Chi-Fung; Chung, Lai-Hon; Tse, Sheung-Ying et al.
In: Chemical Communications, Vol. 56, No. 63, 14.08.2020, p. 8908-8911.Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review