Projects per year
Abstract
Indolizine-fused metallafuran and metal–quinolizinium complexes were synthesized from reactions between dipicolinyl-substituted propargylic alcohol HC≡CC(OH)(CH2(2-py))2 and cis-[Ru/Os(dppm)2Cl2] (dppm = 1,1-bis(diphenylphosphino)methane), revealing the operation of both non-vinylidene and vinylidene pathways regarding the Ru(II)/Os(II)–alkyne interactions. Strategies to control the selectivity of these two competitive pathways were successfully developed, paving ways to the rational design of Ru/Os-induced alkyne activations and metallacycles.
| Original language | English |
|---|---|
| Pages (from-to) | 2458–2466 |
| Journal | Organometallics |
| Volume | 40 |
| Issue number | 15 |
| Online published | 14 Jul 2021 |
| DOIs | |
| Publication status | Published - 9 Aug 2021 |
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Dive into the research topics of 'Controlled Activation of Dipicolinyl-Substituted Propargylic Alcohol by Ru(II) and Os(II) for Unprecedented Indolizine-Fused Metallafuran Complexes'. Together they form a unique fingerprint.Projects
- 2 Finished
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GRF: Constructing Metalated Heterocycles via Alkyne Cycloisomerization: Mechanism and Application
WONG, C. Y. A. (Principal Investigator / Project Coordinator)
1/01/21 → 12/06/25
Project: Research
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TBRS: A Compact System for Terahertz Imaging and Spectroscopy
CHAN, C. H. (Principal Investigator / Project Coordinator), LO, K. W. K. (Co-Principal Investigator), LUK, K. M. (Co-Principal Investigator), PUN, Y. B. E. (Co-Principal Investigator), Pang, S. (Co-Principal Investigator), SHAW, J. (Co-Principal Investigator), VELLAISAMY, A. L. R. (Co-Principal Investigator), CHAN, S. C. (Co-Investigator), DECROZE, C. (Co-Investigator), HO, J. C. Y. (Co-Investigator), JARRAHI, M. (Co-Investigator), LAM, Y. W. (Co-Investigator), LEE, E.-Y. J. (Co-Investigator), LEE, N. P. Y. (Co-Investigator), LEUNG, K. W. (Co-Investigator), LIU, H. (Co-Investigator), QU, S. (Co-Investigator), RENAUD, C. (Co-Investigator), Tong, K. (Co-Investigator), WANG, C. (Co-Investigator), WONG, H. (Co-Investigator), WONG, C. Y. A. (Co-Investigator), WONG, M. H. A. (Co-Investigator) & Wong, K. K. Y. (Co-Investigator)
1/01/17 → 30/06/23
Project: Research