Construction of Complex Co3O4@Co3V2O8 Hollow Structures from Metal–Organic Frameworks with Enhanced Lithium Storage Properties

Yan Lu; Le Yu; Minghong Wu; Yong Wang; Xiong Wen David Lou

doi:10.1002/adma.201702875

Construction of Complex Co₃O₄@Co₃V₂O₈ Hollow Structures from Metal–Organic Frameworks with Enhanced Lithium Storage Properties

Yan Lu
, Le Yu
, Minghong Wu
, Yong Wang
, Xiong Wen David Lou^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

296 Citations (Scopus)

Abstract

A novel metal–organic-framework-engaged strategy is demonstrated for the preparation of multishelled Co3O4@Co3V2O8 hybrid nanoboxes. This strategy relies on the unique reaction of zeolitic imidazolate framework-67 with the vanadium source of vanadium oxytriisopropoxide. Benefitting from the synthetic versatility, a series of nanostructures can be realized including triple-shelled and double-shelled Co3O4@Co3V2O8 nanoboxes and single-shelled Co3V2O8 nanoboxes. When evaluated as electrode materials for lithium-ion batteries, these unique hollow structures demonstrate remarkable lithium storage properties. For example, the triple-shelled Co3O4@Co3V2O8 nanoboxes retain a high capacity of 948 mAh g−1 after 100 cycles at 100 mA g−1. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

Original language	English
Article number	1702875
Journal	Advanced Materials
Volume	30
Issue number	1
DOIs	https://doi.org/10.1002/adma.201702875
Publication status	Published - 4 Jan 2018
Externally published	Yes

Bibliographical note

Publication details (e.g. title, author(s), publication statuses and dates) are captured on an “AS IS” and “AS AVAILABLE” basis at the time of record harvesting from the data source. Suggestions for further amendments or supplementary information can be sent to [email protected].

Funding

X.W.L. acknowledges the funding support from the National Research Foundation (NRF) of Singapore via the NRF Investigatorship (NRF-NRFI2016-04).

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Research Keywords

Co3O4, Co3V2O8
lithium-ion batteries
multishelled
nanoboxes

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10.1002/adma.201702875

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Cite this

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title = "Construction of Complex Co3O4@Co3V2O8 Hollow Structures from Metal–Organic Frameworks with Enhanced Lithium Storage Properties",

abstract = "A novel metal–organic-framework-engaged strategy is demonstrated for the preparation of multishelled Co3O4@Co3V2O8 hybrid nanoboxes. This strategy relies on the unique reaction of zeolitic imidazolate framework-67 with the vanadium source of vanadium oxytriisopropoxide. Benefitting from the synthetic versatility, a series of nanostructures can be realized including triple-shelled and double-shelled Co3O4@Co3V2O8 nanoboxes and single-shelled Co3V2O8 nanoboxes. When evaluated as electrode materials for lithium-ion batteries, these unique hollow structures demonstrate remarkable lithium storage properties. For example, the triple-shelled Co3O4@Co3V2O8 nanoboxes retain a high capacity of 948 mAh g−1 after 100 cycles at 100 mA g−1. {\textcopyright} 2017 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim",

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AU - Lou, Xiong Wen David

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N2 - A novel metal–organic-framework-engaged strategy is demonstrated for the preparation of multishelled Co3O4@Co3V2O8 hybrid nanoboxes. This strategy relies on the unique reaction of zeolitic imidazolate framework-67 with the vanadium source of vanadium oxytriisopropoxide. Benefitting from the synthetic versatility, a series of nanostructures can be realized including triple-shelled and double-shelled Co3O4@Co3V2O8 nanoboxes and single-shelled Co3V2O8 nanoboxes. When evaluated as electrode materials for lithium-ion batteries, these unique hollow structures demonstrate remarkable lithium storage properties. For example, the triple-shelled Co3O4@Co3V2O8 nanoboxes retain a high capacity of 948 mAh g−1 after 100 cycles at 100 mA g−1. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

AB - A novel metal–organic-framework-engaged strategy is demonstrated for the preparation of multishelled Co3O4@Co3V2O8 hybrid nanoboxes. This strategy relies on the unique reaction of zeolitic imidazolate framework-67 with the vanadium source of vanadium oxytriisopropoxide. Benefitting from the synthetic versatility, a series of nanostructures can be realized including triple-shelled and double-shelled Co3O4@Co3V2O8 nanoboxes and single-shelled Co3V2O8 nanoboxes. When evaluated as electrode materials for lithium-ion batteries, these unique hollow structures demonstrate remarkable lithium storage properties. For example, the triple-shelled Co3O4@Co3V2O8 nanoboxes retain a high capacity of 948 mAh g−1 after 100 cycles at 100 mA g−1. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

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