TY - JOUR
T1 - Conductive metal–organic framework with redox metal center as cathode for high rate performance lithium ion battery
AU - Gu, Shaonan
AU - Bai, Zhaowen
AU - Majumder, Soumyadip
AU - Huang, Baoling
AU - Chen, Guohua
PY - 2019/7/31
Y1 - 2019/7/31
N2 - Exploration of new materials for lithium ion battery is a continuous challenge to meet the increasing demand for energy storage. Herein, a novel conductive metal-organic framework Cu3(2,3,6,7,10,11-hexahydroxytriphenylene)2 (Cu3(HHTP)2)is obtained and tested as cathode active material in lithium ion battery. With a working voltage range of 1.7–3.5 V, Cu3(HHTP)2 cathode shows a reversible discharge and charge capacity of ∼95 mA h g−1, which is almost equal to its theoretical value. Impressively, this novel cathode also shows highly stable redox cycling performance at the current rate as high as 20C because of its intrinsic electrical conductivity and two dimensional porous structure. Electrochemical properties and chemical analysis of Cu3(HHTP)2 reveal that the valence change of copper cations in the framework is responsible for the lithium ions insertion/desertion during redox cycles. The first principle calculation also supports this mechanism.
AB - Exploration of new materials for lithium ion battery is a continuous challenge to meet the increasing demand for energy storage. Herein, a novel conductive metal-organic framework Cu3(2,3,6,7,10,11-hexahydroxytriphenylene)2 (Cu3(HHTP)2)is obtained and tested as cathode active material in lithium ion battery. With a working voltage range of 1.7–3.5 V, Cu3(HHTP)2 cathode shows a reversible discharge and charge capacity of ∼95 mA h g−1, which is almost equal to its theoretical value. Impressively, this novel cathode also shows highly stable redox cycling performance at the current rate as high as 20C because of its intrinsic electrical conductivity and two dimensional porous structure. Electrochemical properties and chemical analysis of Cu3(HHTP)2 reveal that the valence change of copper cations in the framework is responsible for the lithium ions insertion/desertion during redox cycles. The first principle calculation also supports this mechanism.
KW - Cathode
KW - Conductive MOF
KW - High rate performance
KW - Redox center
UR - http://www.scopus.com/inward/record.url?scp=85065503308&partnerID=8YFLogxK
UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-85065503308&origin=recordpage
U2 - 10.1016/j.jpowsour.2019.04.087
DO - 10.1016/j.jpowsour.2019.04.087
M3 - RGC 21 - Publication in refereed journal
SN - 0378-7753
VL - 429
SP - 22
EP - 29
JO - Journal of Power Sources
JF - Journal of Power Sources
ER -
