Competitive addition and substitution reactions in the interaction of CpWOs3(CO)9(μ-O)(μ3-CCH2Tol) with phosphorus donors. The crystal structure of CpWOs3(CO)8(PPh2Me)(μ-O)(μ3-CCH2Tol)

Yun Chi; John R. Shapley; Melvyn Rowen Churchill; James C. Fettinger

doi:10.1016/0022-328X(89)87101-3

Author(s)

Yun Chi
John R. Shapley
Melvyn Rowen Churchill
James C. Fettinger

Detail(s)

Original language	English
Pages (from-to)	273-285
Journal / Publication	Journal of Organometallic Chemistry
Volume	372
Issue number	2
Publication status	Published - 15 Aug 1989
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1016/0022-328X(89)87101-3 Final Published version
	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-0011647281&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(13da69c7-f7eb-4526-af21-027b40226d40).html

Abstract

Treatment of a CpWOs₃(CO)₉(μ-O)(μ₃-CCH₂Tol) (1) with excess trimethylphosphite in boiling toluene afforded both an addition product, CpWOs₃(CO)₉(P(OMe)₃)(μ-O)(μ₃-CCH₂-Tol) (3), and a substitution product, CpWOs₃(CO)₈(P(OMe)₃)(μ-O)(μ₃-CCH₂)Tol) (4), isolated as crystalline solids in 32% and 21% yields, respectively. From an analogous reaction of 1 with diphenylmethylphosphine only the substitution product CpWOs₃(CO)₈ (PPh₂Me)(μ-O)(μ₃-CCH₂Tol) (5) was isolated. Complexes 3-5 have been characterized by IR, ¹H and ¹³C NMR, and field desorption mass sepctroscopies. In addition the molecular structure of 5 has been determined by X-ray crystallography.

Citation Format(s)

[ RIS ] [ BibTeX ]

Competitive addition and substitution reactions in the interaction of CpWOs₃(CO)₉(μ-O)(μ₃-CCH₂Tol) with phosphorus donors. The crystal structure of CpWOs₃(CO)₈(PPh₂Me)(μ-O)(μ₃-CCH₂Tol). / Chi, Yun; Shapley, John R.; Churchill, Melvyn Rowen et al.

In: Journal of Organometallic Chemistry, Vol. 372, No. 2, 15.08.1989, p. 273-285.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

Chi, Y, Shapley, JR, Churchill, MR & Fettinger, JC 1989, 'Competitive addition and substitution reactions in the interaction of CpWOs₃(CO)₉(μ-O)(μ₃-CCH₂Tol) with phosphorus donors. The crystal structure of CpWOs₃(CO)₈(PPh₂Me)(μ-O)(μ₃-CCH₂Tol)', Journal of Organometallic Chemistry, vol. 372, no. 2, pp. 273-285. https://doi.org/10.1016/0022-328X(89)87101-3

Chi, Y., Shapley, J. R., Churchill, M. R., & Fettinger, J. C. (1989). Competitive addition and substitution reactions in the interaction of CpWOs₃(CO)₉(μ-O)(μ₃-CCH₂Tol) with phosphorus donors. The crystal structure of CpWOs₃(CO)₈(PPh₂Me)(μ-O)(μ₃-CCH₂Tol). Journal of Organometallic Chemistry, 372(2), 273-285. https://doi.org/10.1016/0022-328X(89)87101-3

Chi Y, Shapley JR, Churchill MR, Fettinger JC. Competitive addition and substitution reactions in the interaction of CpWOs₃(CO)₉(μ-O)(μ₃-CCH₂Tol) with phosphorus donors. The crystal structure of CpWOs₃(CO)₈(PPh₂Me)(μ-O)(μ₃-CCH₂Tol). Journal of Organometallic Chemistry. 1989 Aug 15;372(2):273-285. doi: 10.1016/0022-328X(89)87101-3

Chi, Yun ; Shapley, John R. ; Churchill, Melvyn Rowen et al. / Competitive addition and substitution reactions in the interaction of CpWOs₃(CO)₉(μ-O)(μ₃-CCH₂Tol) with phosphorus donors. The crystal structure of CpWOs₃(CO)₈(PPh₂Me)(μ-O)(μ₃-CCH₂Tol). In: Journal of Organometallic Chemistry. 1989 ; Vol. 372, No. 2. pp. 273-285.