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Coke Formation during Thermal Treatment of Bio-oil

  • Xun Hu*
  • , Zhanming Zhang
  • , Mortaza Gholizadeh*
  • , Shu Zhang
  • , Chun Ho Lam
  • , Zhe Xiong
  • , Yi Wang*
  • *Corresponding author for this work

Research output: Journal Publications and ReviewsRGC 21 - Publication in refereed journalpeer-review

Abstract

Bio-oil is a mixture of organics produced from pyrolysis of biomass. The organics in bio-oil serve as the feedstock for the production of hydrogen, chemicals, biofuels, and carbon materials. In many processes for conversion of bio-oil, heating is required. The thermal treatment of bio-oil induces the polymerization/cracking of the organics in bio-oil, producing coke. Coke could lower the carbon conversion efficiency of bio-oil, clog the reactor chamber, and deactivate the catalyst, imposing the main challenge for the utilization of bio-oil involving the heating of bio-oil. This review investigates the coking issues in the processes for bio-oil upgrading including esterification, hydrotreatment, catalytic pyrolysis, pyrolysis, steam reforming, and the process for the conversion of bio-oil to carbon materials. The properties of coke formed from thermal treatment of bio-oil, the mechanism for coking of bio-oil, and the methods developed for tackling the coking of bio-oil are the focus.
Original languageEnglish
Pages (from-to)7863-7914
JournalEnergy & Fuels
Volume34
Issue number7
Online published12 Jun 2020
DOIs
Publication statusPublished - 16 Jul 2020

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

  1. SDG 7 - Affordable and Clean Energy
    SDG 7 Affordable and Clean Energy
  2. SDG 13 - Climate Action
    SDG 13 Climate Action

Research Keywords

  • CATALYTIC FAST PYROLYSIS
  • NI-BASED CATALYSTS
  • SUPERCRITICAL WATER GASIFICATION
  • RENEWABLE HYDROGEN-PRODUCTION
  • NICKEL-BASED CATALYSTS
  • FLUIDIZED-BED REACTOR
  • NOBLE-METAL CATALYSTS
  • SOLID ACID CATALYST
  • ACETIC-ACID
  • BIOMASS PYROLYSIS

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