Abstract
Bio-oil is a mixture of organics produced from pyrolysis of biomass. The organics in bio-oil serve as the feedstock for the production of hydrogen, chemicals, biofuels, and carbon materials. In many processes for conversion of bio-oil, heating is required. The thermal treatment of bio-oil induces the polymerization/cracking of the organics in bio-oil, producing coke. Coke could lower the carbon conversion efficiency of bio-oil, clog the reactor chamber, and deactivate the catalyst, imposing the main challenge for the utilization of bio-oil involving the heating of bio-oil. This review investigates the coking issues in the processes for bio-oil upgrading including esterification, hydrotreatment, catalytic pyrolysis, pyrolysis, steam reforming, and the process for the conversion of bio-oil to carbon materials. The properties of coke formed from thermal treatment of bio-oil, the mechanism for coking of bio-oil, and the methods developed for tackling the coking of bio-oil are the focus.
| Original language | English |
|---|---|
| Pages (from-to) | 7863-7914 |
| Journal | Energy & Fuels |
| Volume | 34 |
| Issue number | 7 |
| Online published | 12 Jun 2020 |
| DOIs | |
| Publication status | Published - 16 Jul 2020 |
UN SDGs
This output contributes to the following UN Sustainable Development Goals (SDGs)
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SDG 7 Affordable and Clean Energy
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SDG 13 Climate Action
Research Keywords
- CATALYTIC FAST PYROLYSIS
- NI-BASED CATALYSTS
- SUPERCRITICAL WATER GASIFICATION
- RENEWABLE HYDROGEN-PRODUCTION
- NICKEL-BASED CATALYSTS
- FLUIDIZED-BED REACTOR
- NOBLE-METAL CATALYSTS
- SOLID ACID CATALYST
- ACETIC-ACID
- BIOMASS PYROLYSIS
ESI Highly Cited Papers
- Highly Cited Paper 2022
- Highly Cited Paper 2023
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