Co-assembly of Zn(SPh)2 and organic linkers into helical and zig-zag polymer chains

Yi Liu; Ling-Min Yu; Say Chye Joachim Loo; Richard G. Blair; Qichun Zhang

doi:10.1016/j.jssc.2012.03.044

Co-assembly of Zn(SPh)₂ and organic linkers into helical and zig-zag polymer chains

Yi Liu
, Ling-Min Yu
, Say Chye Joachim Loo
, Richard G. Blair
, Qichun Zhang^*

^*Corresponding author for this work

Research output: Journal Publications and Reviews › RGC 21 - Publication in refereed journal › peer-review

18 Citations (Scopus)

Abstract

Two novel one-dimensional coordination polymers, single helicate [Zn(SPh)₂(TPyTA)(EG)]_n(EG=ethylene glycol) (1) and zig-zag structure [Zn(SPh)₂(BPyVB)]_n (2), were synthesized under solvothermal conditions at 150 °C or room temperature by the co-assembly of Zn(SPh)₂ and organic linkers such as 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPyTA) and 1,3-bis(trans-4-pyridylvinyl) benzene (BPyVB). X-ray crystallography study reveals that both polymers 1 and 2 crystallize in space group P2₁/c of the monoclinic system. The solid-state UV-vis absorption spectra show that 1 and 2 have maxium absorption onsets at 400 nm and 420 nm, respectively. TGA analysis indicates that 1 and 2 are stable up to 110 °C and 210 °C. © 2012 Elsevier Inc.

Original language	English
Pages (from-to)	283-286
Journal	Journal of Solid State Chemistry
Volume	191
Online published	28 Mar 2012
DOIs	https://doi.org/10.1016/j.jssc.2012.03.044
Publication status	Published - Jul 2012
Externally published	Yes

Research Keywords

Coordination polymers
Organic linkers
Single helicate
Zig-zag structure

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10.1016/j.jssc.2012.03.044

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title = "Co-assembly of Zn(SPh)2 and organic linkers into helical and zig-zag polymer chains",

abstract = "Two novel one-dimensional coordination polymers, single helicate [Zn(SPh)2(TPyTA)(EG)]n (EG=ethylene glycol) (1) and zig-zag structure [Zn(SPh)2(BPyVB)]n (2), were synthesized under solvothermal conditions at 150 °C or room temperature by the co-assembly of Zn(SPh)2 and organic linkers such as 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPyTA) and 1,3-bis(trans-4-pyridylvinyl) benzene (BPyVB). X-ray crystallography study reveals that both polymers 1 and 2 crystallize in space group P21/c of the monoclinic system. The solid-state UV-vis absorption spectra show that 1 and 2 have maxium absorption onsets at 400 nm and 420 nm, respectively. TGA analysis indicates that 1 and 2 are stable up to 110 °C and 210 °C. {\textcopyright} 2012 Elsevier Inc.",

keywords = "Coordination polymers, Organic linkers, Single helicate, Zig-zag structure, Coordination polymers, Organic linkers, Single helicate, Zig-zag structure, Coordination polymers, Organic linkers, Single helicate, Zig-zag structure",

author = "Yi Liu and Ling-Min Yu and Loo, \{Say Chye Joachim\} and Blair, \{Richard G.\} and Qichun Zhang",

year = "2012",

month = jul,

doi = "10.1016/j.jssc.2012.03.044",

language = "English",

volume = "191",

pages = "283--286",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

}

TY - JOUR

T1 - Co-assembly of Zn(SPh)2 and organic linkers into helical and zig-zag polymer chains

AU - Liu, Yi

AU - Yu, Ling-Min

AU - Loo, Say Chye Joachim

AU - Blair, Richard G.

AU - Zhang, Qichun

PY - 2012/7

Y1 - 2012/7

N2 - Two novel one-dimensional coordination polymers, single helicate [Zn(SPh)2(TPyTA)(EG)]n (EG=ethylene glycol) (1) and zig-zag structure [Zn(SPh)2(BPyVB)]n (2), were synthesized under solvothermal conditions at 150 °C or room temperature by the co-assembly of Zn(SPh)2 and organic linkers such as 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPyTA) and 1,3-bis(trans-4-pyridylvinyl) benzene (BPyVB). X-ray crystallography study reveals that both polymers 1 and 2 crystallize in space group P21/c of the monoclinic system. The solid-state UV-vis absorption spectra show that 1 and 2 have maxium absorption onsets at 400 nm and 420 nm, respectively. TGA analysis indicates that 1 and 2 are stable up to 110 °C and 210 °C. © 2012 Elsevier Inc.

AB - Two novel one-dimensional coordination polymers, single helicate [Zn(SPh)2(TPyTA)(EG)]n (EG=ethylene glycol) (1) and zig-zag structure [Zn(SPh)2(BPyVB)]n (2), were synthesized under solvothermal conditions at 150 °C or room temperature by the co-assembly of Zn(SPh)2 and organic linkers such as 2,4,6-tri(4-pyridyl)-1,3,5-triazine (TPyTA) and 1,3-bis(trans-4-pyridylvinyl) benzene (BPyVB). X-ray crystallography study reveals that both polymers 1 and 2 crystallize in space group P21/c of the monoclinic system. The solid-state UV-vis absorption spectra show that 1 and 2 have maxium absorption onsets at 400 nm and 420 nm, respectively. TGA analysis indicates that 1 and 2 are stable up to 110 °C and 210 °C. © 2012 Elsevier Inc.

KW - Coordination polymers

KW - Organic linkers

KW - Single helicate

KW - Zig-zag structure

KW - Coordination polymers

KW - Organic linkers

KW - Single helicate

KW - Zig-zag structure

KW - Coordination polymers

KW - Organic linkers

KW - Single helicate

KW - Zig-zag structure

UR - https://www.scopus.com/pages/publications/84862216835

UR - https://www.scopus.com/record/pubmetrics.uri?eid=2-s2.0-84862216835&origin=recordpage

U2 - 10.1016/j.jssc.2012.03.044

DO - 10.1016/j.jssc.2012.03.044

M3 - RGC 21 - Publication in refereed journal

SN - 0022-4596

VL - 191

SP - 283

EP - 286

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

ER -

Co-assembly of Zn(SPh)₂ and organic linkers into helical and zig-zag polymer chains

Abstract

Research Keywords

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