Cluster condensation reactions. The synthesis and crystal and molecular structure of Os6(CO)14(μ2-PPh2)2(μ3-S)3(μ4-S)

Richard D. Adams; István T. Horváth; Brigitte E. Segmüller

doi:10.1016/S0022-328X(00)99147-2

Author(s)

Richard D. Adams
István T. Horváth
Brigitte E. Segmüller

Detail(s)

Original language	English
Pages (from-to)	243-252
Journal / Publication	Journal of Organometallic Chemistry
Volume	262
Issue number	2
Publication status	Published - 14 Feb 1984
Externally published	Yes

Link(s)

DOI	DOI https://doi.org/10.1016/S0022-328X(00)99147-2 Final Published version
	Check@CityULib
Link to Scopus	https://www.scopus.com/record/display.uri?eid=2-s2.0-48749140786&origin=recordpage
Permanent Link	https://scholars.cityu.edu.hk/en/publications/publication(3fc22e69-a349-4b67-9d58-2ae5368bb4b0).html

Abstract

Thermal degradation of the cluster compound Os₃(CO)₈(PPh₂H)(μ₃-S)₂ (I) at 125°C leads to decarbonylation and formation of the new ligand bridged hexanuclear cluster Os₆(CO)₁₄(μ-PPh₂)₂(μ₃-S)₃(μ₄-S) (II) in 11% yield. Space Group: P1, No. 2, a 10.427(5), b 13.552(3), c 17.919(3) Å, α 84.87(2), β 75.41(3), γ 78.43(3)°, V 2399(2) Å³ Z = 2, _{ρ{variant}calc} 2.82 g cm^-3. The structure was solved by the heavy atom method and refined (3223 reflections) to the final residuals R = 0.042 and R_w = 0.036. The molecule consists of two sulfido bridged open triosmium clusters which are linked by a bridging sulfido ligand and a bridging diphenylphosphino ligand. © 1984.

Citation Format(s)

[ RIS ] [ BibTeX ]

Cluster condensation reactions. The synthesis and crystal and molecular structure of Os₆(CO)₁₄(μ₂-PPh₂)₂(μ₃-S)₃(μ₄-S). / Adams, Richard D.; Horváth, István T.; Segmüller, Brigitte E.

In: Journal of Organometallic Chemistry, Vol. 262, No. 2, 14.02.1984, p. 243-252.

Research output: Journal Publications and Reviews (RGC: 21, 22, 62) › 21_Publication in refereed journal › peer-review

Adams, RD, Horváth, IT & Segmüller, BE 1984, 'Cluster condensation reactions. The synthesis and crystal and molecular structure of Os₆(CO)₁₄(μ₂-PPh₂)₂(μ₃-S)₃(μ₄-S)', Journal of Organometallic Chemistry, vol. 262, no. 2, pp. 243-252. https://doi.org/10.1016/S0022-328X(00)99147-2

Adams, R. D., Horváth, I. T., & Segmüller, B. E. (1984). Cluster condensation reactions. The synthesis and crystal and molecular structure of Os₆(CO)₁₄(μ₂-PPh₂)₂(μ₃-S)₃(μ₄-S). Journal of Organometallic Chemistry, 262(2), 243-252. https://doi.org/10.1016/S0022-328X(00)99147-2

Adams RD, Horváth IT, Segmüller BE. Cluster condensation reactions. The synthesis and crystal and molecular structure of Os₆(CO)₁₄(μ₂-PPh₂)₂(μ₃-S)₃(μ₄-S). Journal of Organometallic Chemistry. 1984 Feb 14;262(2):243-252. doi: 10.1016/S0022-328X(00)99147-2

Adams, Richard D. ; Horváth, István T. ; Segmüller, Brigitte E. / Cluster condensation reactions. The synthesis and crystal and molecular structure of Os₆(CO)₁₄(μ₂-PPh₂)₂(μ₃-S)₃(μ₄-S). In: Journal of Organometallic Chemistry. 1984 ; Vol. 262, No. 2. pp. 243-252.